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DOI: 10.1039/A802325E (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 1939-1940

Coupling reaction of alkyl cyanide (RCN, R = Me or Et) with 7-azaindole on a hexaosmium carbonyl cluster core; molecular structure of [Os6(CO)14(µ-CO)(µ-H)(µ-η1[hair space]:[hair space]η2-C9H8N3)]

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Kelvin Sze-Yin Leung and Wing-Tak Wong

Abstract

Treatment of [Os6(CO)16(NCR)2] (R = Me or Et) with 7-azaindole resulted in the formation of [Os6(CO)14(µ-CO)(µ-H)(µ-η1∶η2-C8H5N3)(R)] involving coupling of the alkyl cyanide and 7-azaindole.

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