Copper-chalcogenide clusters stabilised with linear bidentate phosphine ligands[hair space]

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Marcus Semmelmann, Dieter Fenske and John F. Corrigan


Abstract

The bidentate phosphine ligands bis(diphenylphosphino)acetylene and 1,4-bis(diphenylphosphino)benzene have been found effectively to stabilise polynuclear copper/chalcogenide/chalcogenolate cores, acting as intramolecular bridges between copper centres. The clusters [Cu16Se4(SePh)8(µ-1,4-Ph2PC6H4PPh2)4] 1 and [Cu25Te6(TeBun)13(µ-Ph2PC[triple bond, length half m-dash]CPPh2)6] 2 and the related binuclear complexes [(BunTe)Cu(µ-Ph2PC[triple bond, length half m-dash]CPPh2)3Cu(TeBun)] 3 and [(PhSe)Cu(µ-Ph2PC[triple bond, length half m-dash]CC[triple bond, length half m-dash]CPPh2)3Cu(SePh)] 4 have been prepared and their molecular structures determined.


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