A new CuI(SCN) structural motif: synthesis of an uncharged three-dimensional co-ordination network

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Alexander J. Blake, Neil R. Champness, Marcello Crew, Lyall R. Hanton, Simon Parsons and Martin Schröder


Abstract

The complex [Cu2(SCN)2(L)] (L = pyrazine) has been prepared and characterised by X-ray diffraction studies revealing a new uncharged three-dimensional co-ordination network consisting of undulating [Cu(SCN)] sheets bridged by pyrazine ligands.


References

  1. T. Iwamoto, S. Nishikiori, T. Kitazawa and H. Yuge, J. Chem. Soc., Dalton Trans., 1997, 4127 RSC; C. Janiak, Angew. Chem., Int. Ed. Engl., 1997, 36, 1431 CrossRef CAS.
  2. A. J. Blake, N. R. Champness, S. S. M. Chung, W.-S. Li and M. Schröder, Chem. Commun., 1997, 1005 RSC; A. J. Blake, N. R. Champness, A. Khlobystov, D. A. Lemenovskii, W.-S. Li and M. Schröder, Chem. Commun., 1997, 1339 RSC; A. J. Blake, N. R. Champness, S. S. M. Chung, W.-S. Li and M. Schröder, Chem. Commun., 1997, 1675 RSC; A. J. Blake, N. R. Champness, A. Khlobystov, D. A. Lemenovskii, W.-S. Li and M. Schröder, Chem. Commun., 1997, 2027 RSC; M. A. Withersby, A. J. Blake, N. R. Champness, P. Hubberstey, W.-S. Li and M. Schröder, Angew. Chem., Int. Ed. Engl., 1997, 36, 2327 CrossRef CAS.
  3. A. J. Blake, N. R. Champness, M. Crew, A. Deveson, D. Fenske, D. H. Gregory, L. R. Hanton, W.-S. Li and M. Schröder, unpublished work.
  4. M. Kabešová, M. Dunaj-Jurčo, M. Serátor, J. Gažo and I. Garja, Inorg. Chim. Acta, 1976, 17, 161 CrossRef CAS.
  5. D. L. Smith and V. I. Saunders, Acta Crystallogr., Sect. B, 1982, 38, 907 CrossRef.
  6. C. L. Raston, B. Walter and A. H. White, Aust. J. Chem., 1979, 32, 2757 CAS.
  7. P. C. Healy, C. Pakawatchai, R. Papasergio, V. A. Patrick and A. H. White, Inorg. Chem., 1984, 23, 3769 CrossRef CAS.
  8. E. Bouwman, W. L. Driessen and J. Reedijk, J. Chem. Soc., Dalton Trans., 1988, 1337 RSC.
  9. S. R. Petrusenko, V. N. Kokozay, O. Y. Vassilyeva and B. W. Skelton, J. Chem. Soc., Dalton Trans., 1997, 1793 RSC; J. Lu, T. Paliwala, S. C. Lim, C. Yu, T. Niu and A. J. Jacobson, Inorg. Chem., 1997, 36, 923 CrossRef CAS; O.-S. Jung, S. H. Park, D. C. Kim and K. M. Kim, Inorg. Chem., 1998, 37, 610 CrossRef.
  10. Advanced Inorganic Chemistry, F. A. Cotton and G. Wilkinson, Wiley, 5th edn., 1988, pp. 757–758 Search PubMed.
  11. Crystal Structures, ed. R. W. G. Wyckoff, Wiley Interscience, New York, 2nd edn., 1963, vol. 1, p. 110 Search PubMed.
  12. O. M. Yaghi and G. Li, Angew. Chem., Int. Ed. Engl., 1995, 34, 207 CrossRef CAS; M. J. Hannon, C. L. Painting and W. Errington, Chem. Commun., 1997, 1805 RSC.
  13. A. L. Spek, PLATON, Acta Crystallogr., Sect. A, 1990, 46, C-34.
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