An unexpected redistribution of trichlorosilane. Synthesis, structure and bonding of (N,N,N′,N′-tetraethylethylenediamine)dichlorosilane
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Philip Boudjouk, Steven D. Kloos, Beon-Kyu Kim, Michael Page and David Thweatt
Abstract
N,N,N′,N′-Tetraethylethylenediamine (teeda) redistributes trichlorosilane to form the novel six-co-ordinate complex, (teeda)SiH2Cl2 and tetrachlorosilane.
References
J. Davy, Philos. Trans., 1812, 102, 352 Search PubMed; H. J. Emeleus and N. J. Miller, J. Chem. Soc., 1939, 819 RSC; A. G. Burg, J. Am. Chem. Soc., 1954, 76, 2674 CrossRefCAS; U. Wannagat, Angew. Chem., 1957, 69, 516; R. Muller, Organomet. Chem. Rev., 1966, 1, 359 Search PubMed; U. Wannagat, K. Hensen, P. Petesch and F. Vielberg, Montatsh. Chem., 1967, 98, 1415 Search PubMed; D. Kummer, A. Balkir and H. Koster, J. Organomet. Chem., 1979, 178, 29 CrossRefCAS; K. Hensen, T. Zengerly, P. Pickel and G. Klebe, Angew. Chem., Int. Ed. Engl., 1983, 22, 725 CrossRef; B. S. Ault and M. L. H. Jeng, Inorg. Chem., 1990, 29, 837 CrossRef; R. R. Holmes, Chem. Rev., 1990, 90, 17 CrossRefCAS; D. Kummer, S. C. Chaudhry, T. Debaerdemaeker and U. Thewalt, Chem. Ber., 1990, 123, 945 CAS; D. Kummer, S. C. Chaudhry, W. Depmeier and G. Mattern, Chem. Ber., 1990, 123, 2241 CAS; R. J. P. Corriu, C. Chuit, C. Reye and J. C. Young, Chem. Rev., 1993, 93, 1371 CrossRefCAS; R. J. P. Corriu, A. Kpoton, M. Poirier, G. Royo, A. de Saxce and J. C. Young, J. Organomet. Chem., 1990, 395, 1 CrossRefCAS; R. J. P. Corriu, C. Chuit, A. Mehdi and C. Reye, Angew. Chem., Int. Ed. Engl., 1993, 32, 1311 CrossRef.
H. J. Campbell-Ferguson and E. A. V. Ebsworth, J. Chem. Soc. A, 1996, 1508 Search PubMed; 1967,
705.
P. Boudjouk, S. Kloos and A. B. Rajkumar, J. Organomet. Chem., 1993, 443, C41 CrossRefCAS; A. B. Rajkumar and P. Boudjouk, Organometallics, 1989, 8, 549 CrossRefCAS.
Some preliminary results on these complexes were reported:
B. K. Kim,
S. D. Kloos and
P. BoudjoukConference on Main Group Chemistry,
Fargo, ND,
May 30–June 1, 1996,
abstract no. P-19 Search PubMed.
H. Fleischer, K. Hensen and T. Stumpt, Chem. Ber., 1996, 129, 765 CrossRefCAS.
C. K. Johnson,
ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN,
1976.
R. J. P. Corriu, C. Reye, J. C. Young and C. Chuit, Chem. Rev., 1993, 93, 1371 CrossRefCAS.
J. M. Wittbrodt and H. B. Schlegel, Chem. Phys. Lett., 1997, 265, 527 CrossRefCAS.
M. S. Gordon, L. P. Davis and L. W. Burggraf, Chem. Phys. Lett., 1989, 163, 371 CrossRefCAS.
L. O. Brockway and I. E. Coop, Trans. Faraday Soc., 1938, 34, 1429 RSC.
L. O. Brockway and J. Y. Beach, J. Am. Chem. Soc., 1938, 60, 1836 CrossRefCAS.
R. J. P. Corriu, C. Reye, J. C. Young and C. Chuit, Chem. Rev., 1993, 93, 1371 CrossRefCAS.
S. N. Sahu, T. S. Shi, P. W. Ge, J. W. Corbett, A. Hiraki, T. Imura, M. Tashiro and V. A. Singh, J. Chem. Phys., 1982, 77, 4330 CrossRefCAS.
Preliminary results have been presented:
W. D. Thweatt,
S. D. Kloos,
B. K. Kim,
M. Page and
P. Boudjouk,
213th ACS meeting,
San Francisco, CA,
April 13–17,
1997,
abstract p243 Search PubMed.
W. Stevens, H. Basch and J. Krauss, J. Chem. Phys., 1984, 81, 6026 CrossRef.
M. S. Gordon, M. T. Garroll, L. P. Davis and L. W. Burggraf, J. Phys. Chem., 1990, 94, 8125 CrossRefCAS.
E. A. Williams,
in Annual Report on NMR Spectroscopy,
ed. G. A. Webb,
Academic Press,
London,
1983,
vol. 15, p. 235 Search PubMed.
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