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DOI: 10.1039/A708910D (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 931-936

Unusual reactions of cationic carbyne complexes of manganese and rhenium with [NMe4][HFe(CO)4] to form heteronuclear dimetal carbene-bridged complexes

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Yongjun Tang, Jie Sun and Jiabi Chen

Abstract

The reaction of a cationic carbyne complex of manganese [Mn([triple bond, length half m-dash]CPh)(η-C5H5)(CO)2]BBr4 1 with the salt [NMe4][HFe(CO)4] 3 in thf at low temperature gave [Mn(η-C5H5)(CO)3] 4 and a novel dimetal carbene-bridged complex [MnFe{µ-C(H)Ph}(η-C5H5)(CO)5] 5. The cationic rhenium carbyne complex [Re([triple bond, length half m-dash]CPh)(η-C5H5)(CO)2]BBr4 2 similarly reacted with 3 to give [Re(η-C5H5)(CO)3] 6 and [ReFe{µ-C(H)Ph}(η-C5H5)(CO)6] 7. Complex 5 reacted with carbon monoxide gas leading to cleavage of the µ-C–Mn and Mn–Fe bonds to afford 4 and a novel benzene-co-ordinated acyltricarbonyliron complex [Fe(PhCHCO)(CO)3] 8. The reaction of 7 with PPh3 yielded [ReFe{µ-C(H)Ph}(η-C5H5)(CO)5(PPh3)] 9. The structures of complexes 5, 8 and 9 have been established by X-ray diffraction studies.

References

  1. C. K. Rofe Depooeter, Chem. Rev., 1981, 81, 447 CrossRef CAS.
  2. G. Wilkinson, F. G. A. Stone and E. W. Abel, Comprehensive Organometallic Chemistry, Pergamon, Oxford, 1982, vol. 8, p. 40 Search PubMed.
  3. T. V. Ashworth, J. A. K. Howard, M. Laguna and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1980, 1593 RSC.
  4. G. A. Carriedo, J. A. K. Howard and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1984, 1555 RSC.
  5. D. Hodgson, J. A. K. Howard, F. G. A. Stone and M. J. Went, J. Chem. Soc., Dalton Trans., 1985, 1331 RSC.
  6. M. U. Pilotti, F. G. A. Stone and I. Topaloglu, J. Chem. Soc., Dalton Trans., 1991, 1621 RSC.
  7. J.-B. Chen, Y. Yu, K. Liu, G. Wu and P.-J. Zheng, Organometallics, 1993, 12, 1213 CrossRef CAS.
  8. Y. Yu, J.-B. Chen, J. Chen and P.-J. Zheng, J. Chem. Soc., Dalton Trans., 1996, 1443 RSC.
  9. E. O. Fischer, E. W. Meineke and F. R. Kreissl, Chem. Ber., 1977, 110, 1140 CrossRef CAS.
  10. E. O. Fischer, J.-B. Chen and K. Scherzer, J. Organomet. Chem., 1983, 253, 231 CrossRef CAS.
  11. T. E. Cole and R. Pettit, Tetrahedron Lett., 1977, 9, 781 CrossRef.
  12. T. S. Piper, F. A. Cotton and G. Wilkinson, J. Inorg. Nucl. Chem., 1955, 1, 165 CrossRef.
  13. E. O. Fischer and W. Fellmann, J. Organomet. Chem., 1963, 1, 191 CrossRef CAS.
  14. N. Walker and D. Stuart, DIFABS, Acta Crystallogr., Sect. A, 1983, 39, 158 CrossRef.
  15. TEXSAN, Structure Analysis Package, Molecular Structure Corporation, Houston, TX, 1985.
  16. J. C. JeVery, I. Moore, H. Razay and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1981, 1255 RSC.
  17. A. Davison, W. McFarlane, L. Pratt and G. Wilkinson, J. Chem. Soc., 1962, 3653 RSC; Inorg. Synth., 1966, 8, 185 Search PubMed.
  18. J. A. Bandy, F. G. N. Cloke, M. L. H. Green, D. O'Hare and K. Prout, J. Chem. Soc., Chem. Commun., 1984, 240 RSC.
  19. V. G. Albano, A. Araneo, P. L. Bellon, G. Ciani and M. Manassero, J. Organomet. Chem., 1974, 67, 413 CrossRef CAS.
  20. P. E. Riley and R. E. Davis, Inorg. Chem., 1980, 19, 159 CrossRef CAS.
  21. J. C. JeVery, J. C. V. Laurie, I. Moore, H. Razay and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1984, 1563 RSC.
  22. J. H. Davis, jun and C. M. Lukehart, Organometallics, 1984, 3, 1763 CrossRef.
  23. T.-A. Mitssudo, T. Sasaki, Y. Watanabe, Y. Takegami, S. Nishigaki and K. Nakatsu, J. Chem. Soc., Chem. Commun., 1978, 252 RSC.
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