DOI: 10.1039/A708210J
(Paper)
Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 511-512
Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand
(Note: The full text of this document is currently only available in the PDF Version )
Hidehito Komatsuzaki, Yuichi Nagasu, Kantaro Suzuki, Takao Shibasaki, Minoru Satoh, Fujio Ebina, Shiro Hikichi, Munetaka Akita and Yoshihiko Moro-oka
Abstract
Reaction of a MnII thiolate complex bearing hydrotris(3,5-diisopropylpyrazol-1-yl)borate with O2 resulted in O–O bond activation to give a dinuclear MnIII bis(µ-oxo) complex and a ligand-oxygenated dinuclear MnIII µ-oxo complex, or the dinuclear MnIII,IV µ-acetato-bis(µ-oxo) complex in the presence of a MnII acetate complex.
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