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DOI: 10.1039/A708168E (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 513-514

Synthesis and structural characterisation of tetraruthenium µ4-nitrene clusters containing tolylacetylene (HC2Tol). Molecular structures of [Ru4(CO)9(µ-CO)2(µ4-NH)(µ4-η2-HC2Tol)] and [Ru4(CO)9(µ-CO)2{µ4-NC(O)OMe}(µ4-η2-HC2Tol)]

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Emmie Ngai-Man Ho and Wing-Tak Wong

Abstract

Two structurally characterized tetraruthenium carbonyl clusters, [Ru4(CO)9(µ-CO)2(µ4-NH)(µ4-η2-HC2Tol)] 1 and [Ru4(CO)9(µ-CO)2{µ4-NC(O)OMe}(µ4-η2-HC2Tol)] 2, have been isolated from the reaction between [Ru3(CO)9(µ3-CO)(µ3-NOMe)] and tolylacetylene (HC2Tol) in refluxing n-octane.

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