View PDF Version
 
DOI: 10.1039/A706363F (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1998, 5-6

A novel two-dimensional rectangular network. Synthesis and structure of {[Cu(4,4′-bpy)(pyz)(H2O)2][PF6]2}n (4,4′-bpy = 4,4′-bipyridine, pyz = pyrazine)

(Note: The full text of this document is currently only available in the PDF Version )

Ming-Liang Tong, Xiao-Ming Chen, Xiao-Lan Yu and Thomas C. W. Mak

Abstract

The complex {[Cu(4,4′-bpy)(pyz)(H2O)2][PF6]2}n comprising two-dimensional rectangular grids with each cavity enclosed by two 4,4′-bipyridine (4,4′-bipy) and two pyrazine (pyz) ligands, which superpose in an off-set fashion to give smaller rectangular channels, has been prepared and characterized by single-crystal X-ray structural analysis.

References

  1. (a) R. Robin, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Huskiness and J. Lieu, Supramolecular Architecture, ACS publications, Washington, DC, 1992, p. 256 Search PubMed; (b) J. M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995, ch. 9 Search PubMed.
  2. C. B. Aakeroy and K. R. Seddon, Chem. Soc. Rev., 1993, 397 RSC.
  3. R. V. Slone, J. T. Hupp, C. L. Stern and T. E. Albrecht-Schmitt, Inorg. Chem., 1996, 35, 4096 CrossRef CAS.
  4. (a) L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Chem. Soc., Chem. Commun., 1994, 2755 RSC; (b) O. M. Yaghi and H. Li, J. Am. Chem. Soc., 1995, 117, 10 401 CrossRef CAS.
  5. G. B. Gardner, D. Venkataraman, J. S. Moore and S. Lee, Nature (London), 1995, 374, 792 CrossRef CAS.
  6. R. W. Gable, B. F. Hoskins and R. Robson, J. Chem. Soc., Chem. Commun., 1990, 1677 RSC; M. Fujita, Y. J. Kwon, S. W. Ashizu and K. Ogura, J. Am. Chem. Soc., 1994, 116, 1151 CrossRef CAS; X.-M. Chen, M.-L. Tong, Y.-J. Luo and Z.-N. Chen, Aust. J. Chem., 1996, 49, 835 CAS; J. Blake, S. J. Hill, P. Hubberstey and W. S. Li, J. Chem. Soc., Dalton Trans., 1997, 913 RSC.
  7. O. M. Yaghi and H. Li, J. Am. Chem. Soc., 1996, 118, 295 CrossRef CAS.
  8. (a) M. Fujita, Y. J. Kwon, Y. O. Sasaki, K. Yamaguchi and K. Ogura, J. Am. Chem. Soc., 1995, 117, 7287 CrossRef CAS; (b) P. Losier and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1996, 35, 2779 CrossRef CAS; (c) T. L. Hennigar, D. C. MacQuarrie, P. Losier, R. D. Rogers and M. J. Zaworotko, ibid., 1997, 36, 972 Search PubMed.
  9. T. Soma, H. Yuge and T. Iwamoto, Angew. Chem., Int. Ed. Engl., 1994, 33, 1665 CrossRef.
  10. S. Kawata, S. Kitagawa, M. Konda, I. Furuchi and M. Munakata, Angew. Chem., Int. Ed. Engl., 1994, 33, 1759 CrossRef.
  11. M.-L. Tong, B.-H. Ye and X.-M. Chen, unpublished work.
  12. G. M. Sheldrick, SHELXTL-PC User's Manual, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1990 Search PubMed.
  13. G. M. Sheldrick, SHELXL 93, Program for X-Ray Crystal Structure Refinement, University of Göttingen, 1993.
  14. C. K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
  15. W. Hölderich, M. Hesse and F. Näumann, Angew. Chem., Int. Ed. Engl., 1988, 27, 226 CrossRef.
  16. J.-M. Li, H.-Q. Zeng, J.-H. Chen, Q.-M. Wang and X.-T. Wu, Chem. Commun., 1997, 1213 RSC.
  17. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, Angew. Chem., Int. Ed. Engl., 1995, 34, 1895 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.