A range of metal thioether macrocyclic complexes has been used as templating agents in the preparation of extended multi-dimensional polyiodide arrays. A selection of unusual and intriguing polyiodides is described, and the role played by the size, shape and charge of the metal macrocyclic complex discussed.
A. J. Blake, W. Li, V. Lippolis, M. Schröder, F. A. Devillanova, R. O. Gould, S. Parsons and C. Radek, Chem. Soc. Rev., 1998, 27, 195 DOI: 10.1039/A827195Z
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