[(silox)2ReO]2 (silox = tBu3SiO) contains a Re[triple bond, length half m-dash]Re bond and terminal oxo ligands

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Richard E. Douthwaite, Peter T. Wolczanski and Erika Merschrod


Abstract

The preference for terminal rather than bridging {i.e. [(silox)2Re]2(µ-O)2} oxo ligands in C2 (silox)2(O)Re[triple bond, length half m-dash]Re- (O)(silox)2 is electronic, not steric, in origin.


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