DOI: 10.1039/A808130A
(Paper)
Reference Section for: Chem. Commun., 1998, 2627-2628
Synthesis and structural characterisation of platinum silasesquioxane complexes
(Note: The full text of this document is currently only available in the PDF Version )
Hendrikus C. L. Abbenhuis, Rutger A. van Santen, Andrew D. Burrows, Mark T. Palmer, Huub Kooijman, Martin Lutz and Anthony L. Spek
Abstract
The reaction of partially condensed silasesquioxanes of the type [R17Si7O9(OH)2(OR2)] (R1 = c-C5H9, c-C6H11; R2 = H, SiMe3) with either [Pt(dppe)(CO3)] or [Pt(dppe)Cl2]/Ag2O leads to the formation of [R17Si7O9(OR2)O2Pt(dppe)], crystallographically characterised for R1 = c-C5H9; R2 = SiMe3, providing unprecedented routes to late transition metal silasesquioxane complexes.
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