Aromatic inclusion within a neutral cavity-containing rectangular grid

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Ryan H. Groeneman, Leonard R. MacGillivray and Jerry L. Atwood


Abstract

Reaction of CoCl2·6H2O with pyrazine and disodium terephthalate in water results in the formation of a neutral cavity-containing rectangular grid, [Co(pyz)(terph)(H2O)2], which includes a tightly bound aromatic as a guest; classification of these frameworks also provides targets for chemical synthesis.


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