Crystalline silica prepared at room temperature from aqueous solution in the presence of intrasilica bioextracts

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Carole C. Perry and Tracey Keeling-Tucker


Abstract

Silica, exhibiting crystalline texture has been prepared from aqueous solution at pH ca. 7 in the presence of intrasilica biomolecules extracted from the primitive plant Equisetum telmateia; some of the silica shows interplanar lattice spacings of 3.5 Å and is present in lath-like objects up to ca. 20–30 nm wide and more than 100 nm in length; an electron diffraction pattern obtained from this material also shows interplanar spacings of 3.46, 2.13 and 1.70 Å suggesting that the material might be quartz.


References

  1. Biomineralization: Chemical and Biochemical Perspectives, ed. S. Mann, J. Webb and R. J. P. Williams, VCH, Weinheim, 1989 Search PubMed.
  2. H. Lowenstam and S. Weiner, On Biomineralization, OUP, Oxford, 1989 Search PubMed.
  3. S. Weiner, J. Exptl. Zool., 1985, 234, 7 Search PubMed.
  4. A. Berman, J. Hanson, L. Leiserowitz, T. Koetzle, S. Weiner and L. Addadi, Science, 1993, 259, 776.
  5. C. C. Harrison (now Perry), Phytochemistry, 1996, 41, 37 CrossRef.
  6. N. Kröger, G. Lehmann, R. Rachel and M. Sumper, Eur. J. Biochem., 1997, 250, 99 CrossRef CAS.
  7. K. Shimizu, J. Cha, G. D. Stucky and D. E. Morse, Proc. Natl. Acad. Sci., 1998, 95, 6234 CrossRef CAS.
  8. C. C. Perry, in Biomineralization: Chemical and Biochemical Perspectives, ed. S. Mann, J. Webb and R. J. P. Williams, VCH, Weinheim, 1989, p. 223 Search PubMed.
  9. C. W. Li and B. E. Volcani, Philos. Trans. R. Soc. London Sect. B, 1984, 304, 519 Search PubMed.
  10. C. C. Perry and Y. Lu, J. Chem. Soc., Faraday Trans., 1992, 88, 2915 RSC.
  11. R. K. Iler, The Chemistry of Silica, Wiley-Interscience, 1979 Search PubMed.
  12. C. C. Harrison (now Perry) and N. Loton, J. Chem. Soc., Faraday Trans., 1995, 91, 4287 RSC.
  13. G. C. Miller and G. N. Miller, Significant Tests in Statistics for Analytical Chemistry, Ellis Horwood, 3rd edn., 1993 Search PubMed.
  14. Y. Rosenfeld Hacohen, E. Grunbaum, R. Tenne, J. Sloan and J. L. Hutchison, Nature, 1998, 395, 336 CrossRef.
  15. R. E. Marsh, R. B. Corey and L. Pauling, Biochim. Biophys. Acta, 1955, 16, 1 CrossRef CAS.
  16. H. Harder and W. Flehmig, Geochim. Cosmochim. Acta, 1970, 34, 295 CrossRef CAS.
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