Spectroscopic characterisation of a copper(II) complex of a thioether-substituted phenoxyl radical: a new model for galactose oxidase

(Note: The full text of this document is currently only available in the PDF Version )

Malcolm A. Halcrow, Li Mei Lindy Chia, John E. Davies, Xiaoming Liu, Lesley J. Yellowlees, Eric J. L. McInnes and Frank E. Mabbs


Abstract

The EPR-silent species [Cu(L2)(TpPh)]+ exhibits a UV–VIS–NIR spectrum that is very similar to that of active galactose oxidase.


References

  1. J. P. Klinman, Chem. Rev., 1996, 96, 2541 CrossRef CAS.
  2. N. Ito, S. E. V. Phillips, C. Stevens, Z. B. Ogel, M. J. McPherson, J. N. Keen, K. D. S. Yadav and P. F. Knowles, Nature, 1991, 350, 87 CrossRef CAS.
  3. M. M. Whittaker and J. W. Whittaker, J. Biol. Chem., 1990, 265, 9610 CAS.
  4. G. Casiraghi, G. Casnati, G. Pugli, G. Sartori and G. Terenghi, J. Chem. Soc., Perkin Trans. 1, 1980, 1862 RSC.
  5. Y. Wang and T. D. P. Stack, J. Am. Chem. Soc., 1996, 118, 13 097 CrossRef CAS.
  6. D. M. Eichhorn and W. H. Armstrong, Inorg. Chem., 1990, 29, 3607 CrossRef CAS.
  7. M. A. Halcrow, E. J. L. McInnes, F. E. Mabbs, I. J. Scowen, M. McPartlin, H. R. Powell and J. E. Davies, J. Chem. Soc., Dalton Trans., 1997, 4025 RSC.
  8. A. R. Forrester, J. M. Hay and R. H. Thomson, Organic Chemistry of Stable Free Radicals, Academic Press, London, 1968, ch. 7, pp. 281–341 Search PubMed.
  9. J. L. Stickney, M. P. Soriaga, A. T. Hubbard and S. E. Anderson, J. Electroanal. Chem. Interfacial. Chem., 1981, 125, 73 Search PubMed.
  10. D. Zurita, I. Gautier-Luneau, S. Ménage, J.-L. Pierre and E. Saint-Aman, J. Biol. Inorg. Chem., 1997, 2, 46 CrossRef CAS; J. A. Halfen, B. A. Jadzdzewski, S. Mahaptara, L. M. Berreau, E. C. Wilkinson, L. Que jr. and W. B. Tolman, J. Am. Chem. Soc., 1997, 119, 8217 CrossRef CAS; J. Müller, T. Weyhermüller, E. Bill, P. Hildenbracht, L. Ould-Moussa, T. Glaser and K. Wieghardt, Angew. Chem., Int. Ed. Engl., 1998, 37, 616 CrossRef CAS.
  11. M. M. Whittaker, P. J. Kersten, N. Nakamura, J. Sanders-Loehr, E. S. Schweizer and J. W. Whittaker, J. Biol. Chem., 1996, 271, 681 CrossRef CAS.
  12. M. L. McGlashen, D. D. Eads, T. G. Spiro and J. W. Whittaker, J. Phys. Chem., 1995, 99, 4918 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.