DOI: 10.1039/A806829A
(Paper)
Reference Section for: Chem. Commun., 1998, 2541-2542
Novel catalysts for thiophene synthesis at lower temperatures
(Note: The full text of this document is currently only available in the PDF Version )
Barry W. L. Southward, Lance S. Fuller, Russell A. Stewart, Graham J. Hutchings and Richard W. Joyner
Abstract
Thiophenes can be synthesised in high yields from the reaction of C4+ oxygenates and CS2 at temperatures 140 °C lower than current industrial catalysts, using novel materials based upon chromium substituted iron oxide hydroxide.
References
- L. S. Fuller, Thiophene and Thiophene Derivatives, in Kirk-Othmer Encyclopaedia of Chemical Technology, 4th edn., Wiley, London, 1997, vol. 24, p. 34 Search PubMed.
- R. Prins, V. J. H. de Beer and G. A. Somorjai, Catal. Rev. Sci. Eng., 1989, 31, 1 Search PubMed.
- N. R. Clark and W. E. Webster, Br. Pat., 1,345,203 (Synthetic Chemicals Ltd.).
- J. Barrault, M. Guisnet, R. Lucien and R. Maurel, J. Chem. Res., 1978, (S) 207; (M) 2634 Search PubMed (US Pat. 4,143,052).
- R. W. Grose and E. M. Flanigen, Preparation of Catalysts 1, eds. B. Delmon, P. A. Jacobs and G. Poncelet, Elsevier, Amsterdam, 1976, p. 51 Search PubMed.
- B. W. L. Southward, PhD Thesis, University of Liverpool, 1993.
- NIST XRD database.
- B. W. L. Southward, G. J. Hutchings, R. W. Joyner, L. S. Fuller and R. A. Stewart, Eur. Pat. 751,139, 1997.