A three-coordinate copper(I)-phenoxide complex that models the reduced form of galactose oxidase

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Brian A. Jazdzewski, Victor G. Young Jr. and William B. Tolman


Abstract

A novel 3-coordinate Cu(I)-phenoxide complex with N-donor supporting ligation was structurally characterized and shown to be highly reactive towards dioxygen, similar to the reduced form of galactose oxidase.


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  16. We thank the NIH (GM47365.), the NSF (NYI Award to W. B. T.), and the Sloan and Camille and Henry Dreyfus Foundations (fellowships to W. B. T.) for funding this research.
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