C60 degrades to C120O

(Note: The full text of this document is currently only available in the PDF Version )

Roger Taylor, Mark P. Barrow and Thomas Drewello


Abstract

At ambient temperature and in the solid state C60 degrades to C120O which is present in up to ca. 1% concentration in each of thirteen differently sourced samples examined; traces of C120O2 have also been detected.


References

  1. R. Taylor, J. P. Hare, A. K. Abdul-Sada and H. W. Kroto, J. Chem. Soc., Chem. Commun., 1990, 1423 RSC.
  2. Reported subsequently, (R. Taylor, Interdisciplinary Science Reviews, 1992, 17, 161.) Search PubMed.
  3. R. Taylor, Molecular Nanostructures, eds. H. Kuzmany, J. Fink, M. Nehring and S. Roth, World Scientific, 1998, p. 136 Search PubMed.
  4. R. Taylor, A. Pénicaud and N. J. Tower, Chem. Phys. Lett., in press Search PubMed.
  5. S. Lebedkin, S. Ballenweg, J. Cross, R. Taylor and W. Krätschmer, Tetrahedron Lett., 1995, 4571.
  6. A. Gromov, S. Lebedkin, S. Ballenweg, A. G. Avent, R. Taylor and W. Krätschmer, Chem. Commun., 1997, 209 RSC.
  7. M. Krause, L. Dunsch, G. Siefert, P. W. Fowler, A. Gromov, W. Krätschmer, R. Gutierez, D. Porezag and T. Frauenheim, J. Chem. Soc., Faraday Trans., 1998, 94, 2287 RSC.
  8. A. B. Smith, H. Toyuyama, R. M. Strongin, G. T. Furst, W. J. Romanov, B. T. Chait, U. A. Mirza and I. Haller, J. Am. Chem. Soc., 1995, 117, 9359 CrossRef.
  9. A. L. Balch, D. A. Costa, W. R. Fawcett and K. Winkler, J. Phys. Chem., 1996, 100, 4823 CrossRef CAS.
  10. K. M. Creegan, J. L. Robbins, W. K. Robbins, J. M. Millar, R. D. Sherwood, P. J. Tindall, D. M. Cox, J. M. McCauley, D. R. Jones, R. Gallagher and A. B. Smith, J. Am. Chem. Soc., 1992, 114, 1103 CrossRef CAS; S. W. McElvany, J. H. Callahan, M. M. Ross, L. D. Lamb and D. R. Huffman, Science, 1993, 260, 1632 CAS.
  11. L. Juha, V. Hamplová, J. Kodymoná and O. Spalek, J. Chem. Soc., Chem. Commun., 1994, 2437 RSC.
  12. Y. Elemes, S. K. Silverman, C. Sheu, M. Kao, C. S. Foote, M. N. Alvarez and R. Whetten, Angew. Chem. Intl. Ed. Engl., 1992, 31, 351 CrossRef.
  13. T. Hamano, T. Mashino and M. Hiroba, J. Chem. Soc., Chem. Commun., 1995, 1537 RSC.
  14. R. W. Murray and K. Iyanar, Tetrahedron Lett., 1997, 38, 335 CrossRef CAS.
  15. D. Heymann and L. P. F. Chibante, Recl. Trav. Chim. Pays-Bas, 1993, 112, 531, 639; Chem. Phys. Lett., 1993, 207, 339 Search PubMed; R. Malhotra, S. Kumar and A. Satyam, J. Chem. Soc., Chem. Commun., 1994, 1339 Search PubMed; J. Deng, C. Mou and C. Han, J. Phys. Chem., 1995, 99, 14907 RSC; J. Deng, D. Ju, G. Her, C. Mou, C. Chen, Y. Lin and C. Han, J. Phys. Chem., 1993, 97, 11575 CrossRef CAS.
  16. T. Nogami, M. Tsuda, T. Ishida, S. Kurono and M. Ohashi, Fullerene Sci. Technol., 1993, 1, 275 CAS; A. L. Balch, D. A. Costa, B. C. Noll and M. M. Olmstead, J. Am. Chem. Soc., 1995, 117, 8926 CrossRef CAS.
  17. W. A. Kalsbeck and H. H. Thorp, J. Electroanal. Chem., 1991, 314, 363 CrossRef CAS.
  18. P. W. Fowler, D. Mitchell, R. Taylor and G. Seifert, J. Chem. Soc., Perkin Trans. 2, 1997, 1901 RSC.
  19. T. K. Daly, P. R. Buseck, P. Williams and C. F. Lewis, Science, 1993, 259, 1599 CAS; D. Heymann, L. P. F. Chibante, W. S. Wolbach, R. R. Brooks and R. E. Smalley, Science, 1994, 265, 645 CAS.
  20. O. V. Boltalina, J. M. Street and R. Taylor, Chem. Commun., 1998, 1827 RSC; A. D. Darwish, P. R. Birkett, G. J. Langley, H. W. Kroto, R. Taylor and D. R. M. Walton, Fullerene Sci. Technol., 1997, 5, 1667 CAS.