Synthesis of extended α,α′-oligo(silylthiophenes) by cerium(IV) oxidative coupling reactions

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Ali H. Mustafa and Michael K. Shepherd


Abstract

Cerium(IV) oxidative dimerisations of 4,4′-bis(trimethylsilyl)-2,2′:5′,2′′-terthiophene and the quaterthienyl analogue 1c gave the corresponding sexi- and octi-thiophenes; the latter have been used to prepare α-linked hexadecithiophene and tetracosithiophene derivatives.


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