A remarkable Mo catalyst for olefin metathesis: hexagonal mesoporous silica-supported molybdenum oxide (MoO3/HMS)
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Tooru Ookoshi and Makoto Onaka
Abstract
Hexagonal mesoporous silica-supported molybdenum oxide exhibits much higher catalytic activity for the metathesis of oct-1-ene in the liquid phase, compared with MoO3 on normal porous silica and MoO3 on γ-alumina.
References
T. Yanagisawa, T. Shimizu, K. Kuroda and C. Sato, Bull. Chem. Soc. Jpn., 1990, 63, 988 CrossRefCAS; S. Inagaki, Y. Fukushima and K. Kuroda, J. Chem. Soc., Chem. Commun., 1993, 680 RSC.
C. T. Kresge, M. E. Leonowicz, R. J. Roth, J. C. Vartuli and J. B. Beck, Nature, 1992, 359, 710 CrossRefCAS; J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, J. B. Higgins and L. Schlenker, J. Am. Chem. Soc., 1992, 114, 10 834 CrossRefCAS.
T. Shinoda, Y. Izumi and M. Onaka, J. Chem. Soc., Chem. Commun., 1995, 1801 RSC.
T. Maschmeyer, F. Rey, G. Sankar and J. M. Thomas, Nature, 1995, 378, 159 CrossRefCAS.
J. Tudor and D. O'Hare, Chem. Commun., 1997, 603 RSC.
K. Weissermel and
H.-J. Arpe,
Industrielle Organische Chemie,
VCH,
Weinheim, 4th edn.,
1994 Search PubMed.
T. Sodesawa, E. Ogata and Y. Kamiya, Bull. Chem. Soc. Jpn., 1979, 52, 1661 CAS.
R. F. Howe and C. Kemball, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 1153 RSC.
Y. I. Yermakov, B. N. Kuznetsov and A. N. Startsev, Kinet. Katal., 1974, 15, 539 Search PubMed.
P. T. Tanev and T. J. Pinnavaia, Science, 1995, 267, 865 CrossRefCAS.
V. I. Bykov, T. A. Butenko, E. S. Finkel'shtein, P. V. Petrovskii and V. M. Vdovin, Izv. Akad. Nauk SSSR, Ser. Khim., 1988, 37, 1580 Search PubMed.
B. N. Shelimov, I. V. Elev and V. B. Kazansky, J. Mol. Catal., 1988, 46, 187 CrossRef.
γ-Alumina [N611(N) from Nikki Chemical Co.; specific surface
area 181 m2 g–1, pore volume 0.36 ml g–1] was used.
A. Ismayel-Milanovic, J. M. Basset, H. Praliaud, M. Dufaux and L. de Mourgues, J. Catal., 1973, 31, 408 CrossRefCAS.
R. Nakamura, H. Iida and E. Echigoya, Chem. Lett., 1972, 273 CAS.
Al2O3-supported MoO3 catalysts (0.15 g) were used in the metathesis.
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