A remarkable Mo catalyst for olefin metathesis: hexagonal mesoporous silica-supported molybdenum oxide (MoO₃/HMS)

Abstract

Hexagonal mesoporous silica-supported molybdenum oxide exhibits much higher catalytic activity for the metathesis of oct-1-ene in the liquid phase, compared with MoO₃ on normal porous silica and MoO₃ on γ-alumina.

References

1. T. Yanagisawa, T. Shimizu, K. Kuroda and C. Sato, Bull. Chem. Soc. Jpn., 1990, 63, 988; S. Inagaki, Y. Fukushima and K. Kuroda, J. Chem. Soc., Chem. Commun., 1993, 680.
2. C. T. Kresge, M. E. Leonowicz, R. J. Roth, J. C. Vartuli and J. B. Beck, Nature, 1992, 359, 710; J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, J. B. Higgins and L. Schlenker, J. Am. Chem. Soc., 1992, 114, 10 834.
3. T. Shinoda, Y. Izumi and M. Onaka, J. Chem. Soc., Chem. Commun., 1995, 1801.
4. T. Maschmeyer, F. Rey, G. Sankar and J. M. Thomas, Nature, 1995, 378, 159.
5. J. Tudor and D. O'Hare, Chem. Commun., 1997, 603.
6. K. Weissermel and H.-J. Arpe, Industrielle Organische Chemie, VCH, Weinheim, 4th edn., 1994.
7. T. Sodesawa, E. Ogata and Y. Kamiya, Bull. Chem. Soc. Jpn., 1979, 52, 1661.
8. R. F. Howe and C. Kemball, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 1153.
9. Y. I. Yermakov, B. N. Kuznetsov and A. N. Startsev, Kinet. Katal., 1974, 15, 539.
10. P. T. Tanev and T. J. Pinnavaia, Science, 1995, 267, 865.
11. V. I. Bykov, T. A. Butenko, E. S. Finkel'shtein, P. V. Petrovskii and V. M. Vdovin, Izv. Akad. Nauk SSSR, Ser. Khim., 1988, 37, 1580.
12. B. N. Shelimov, I. V. Elev and V. B. Kazansky, J. Mol. Catal., 1988, 46, 187.
13. γ-Alumina [N611(N) from Nikki Chemical Co.; specific surface area 181 m² g^–1, pore volume 0.36 ml g^–1] was used.
14. A. Ismayel-Milanovic, J. M. Basset, H. Praliaud, M. Dufaux and L. de Mourgues, J. Catal., 1973, 31, 408.
15. R. Nakamura, H. Iida and E. Echigoya, Chem. Lett., 1972, 273.
16. Al₂O₃-supported MoO₃ catalysts (0.15 g) were used in the metathesis.