View PDF Version
 
DOI: 10.1039/A806077K (Paper) Reference Section for: Chem. Commun., 1998, 2233-2234

[Tl(OPPh3)2][Au(C6F5)2]: the first extended unsupported gold–thallium linear chain

(Note: The full text of this document is currently only available in the PDF Version )

Olga Crespo, Antonio Laguna, Eduardo J. Fernández, José M. López-de-Luzuriaga, Aránzazu Mendía, Miguel Monge, Elena Olmos and Peter G. Jones

Abstract

Li[Au(C6F5)2] reacts with TlNO3 in the presence of OPPh3 affording a complex of stoichiometry [AuTl(C6F5)2- (OPPh3)2]n, which presents different luminescence properties depending on the conditions and whose crystal structure reveals the existence of unsupported Au–Tl bonds forming a polymeric linear chain.

References

  1. P. Pyykkö and F. Mendizabal, Inorg. Chem., 1998, 37, 3018 CrossRef.
  2. P. Pyykkö, Chem. Rev., 1997, 97, 597 CrossRef.
  3. S. Wang, G. Garzón, C. King, J.-C. Wang and J. P. Fackler, Jr., Inorg. Chem., 1989, 28, 4623 CrossRef CAS.
  4. J. S. Miller, Extended Linear Chain Compounds, Plenum, New York and London, 1981–1983, vol. 1–3 Search PubMed.
  5. J. K. Nagle, A. L. Balch and M. M. Olmstead, J. Am. Chem. Soc., 1988, 110, 319 CrossRef CAS.
  6. T. Ziegler, J. K. Nagle, J. G. Snijders and E. J. Baerends, J. Am. Chem. Soc., 1989, 111, 5631 CrossRef CAS.
  7. M. Dolg, P. Pyykkö and N. Runeberg, Inorg. Chem., 1996, 35, 7450 CrossRef CAS.
  8. S. Wang, J. P. Fackler, Jr., C. King and J.-C. Wang, J. Am. Chem. Soc., 1988, 110, 3308 CrossRef CAS.
  9. R. Usón, A. Laguna, M. Laguna, P. G. Jones and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 1981, 1097 RSC.
  10. R. Usón, A. Laguna, M. Laguna, B. R. Manzano, P. G. Jones and G. M. Sheldrick, J. Chem. Soc., Dalton Trans., 1984, 285 RSC.
  11. K. Moss, R. V. Parish, A. Laguna, M. Laguna and R. Usón, J. Chem. Soc., Dalton Trans., 1983, 2071 RSC.
  12. J. D. Basil, H. H. Murray, J. P. Fackler, Jr., J. Tocher, A. M. Mazany, B. Trzcinska-Bancroft, H. Knachel, D. Dudis, T. J. Delord and D. O. Marler, J. Am. Chem. Soc., 1985, 107, 6908 CrossRef CAS.
  13. H. Schmidbaur, C. Hartmann, J. Riede, B. Huber and G. Müller, Organometallics, 1986, 5, 1652 CrossRef CAS.
  14. R. Usón, A. Laguna, M. Laguna, M. T. Tartón and P. G. Jones, J. Chem. Soc., Chem. Commun., 1988, 740 RSC.
  15. SHELX-93, A Program for Refining Crystal Structures, G. M. Sheldrick, University of Göttingen, Germany.
Click here to see how this site uses Cookies. View our privacy policy here.