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DOI: 10.1039/A805956J (Paper) Reference Section for: Chem. Commun., 1998, 2579-2580

Synthesis and structure of a tetranuclear niobium telluride cuboidal cluster with a central µ4-O ligand

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Vladimir P. Fedin, Irina V. Kalinina, Alexander V. Virovets, Nina V. Podberezskaya, Ivan S. Neretin and Yuri L. Slovokhotov

Abstract

High-temperature reaction of NbTe4 with KCN at 450 °C and further crystallization from aqueous solution produces an oxygen-centered tetranuclear niobium cubane-type complex, isolated here as K6[Nb4OTe4(CN)12]·K2CO3·KOH· 8H2O, and characterized by X-ray crystallography.

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