Synthesis and structure of a tetranuclear niobium telluride cuboidal cluster with a central µ4-O ligand

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Vladimir P. Fedin, Irina V. Kalinina, Alexander V. Virovets, Nina V. Podberezskaya, Ivan S. Neretin and Yuri L. Slovokhotov


Abstract

High-temperature reaction of NbTe4 with KCN at 450 °C and further crystallization from aqueous solution produces an oxygen-centered tetranuclear niobium cubane-type complex, isolated here as K6[Nb4OTe4(CN)12]·K2CO3·KOH· 8H2O, and characterized by X-ray crystallography.


References

  1. J. D. Corbett, J. Chem. Soc., Dalton. Trans., 1996, 575 RSC and references therein.
  2. W. Tremel, J. Chem. Soc., Chem. Commun., 1992, 709 RSC.
  3. A. Simon, Z. Anorg. Allg. Chem., 1967, 355, 311 CrossRef CAS.
  4. J. Sola, Y. Do, J. M. Bergand and R. H. Holm, Inorg. Chem., 1985, 24, 1706 CrossRef CAS.
  5. J. R. Rambo, J. C. Huffman, G. Christou and O. Eisenstein, J. Am. Chem. Soc., 1989, 111, 8027 CrossRef CAS.
  6. (a) F. A. Cotton and M. Shang, Inorg. Chem., 1990, 29, 2619 CrossRef CAS; (b) F. A. Cotton and M. Shang, J. Am. Chem. Soc., 1990, 112, 1584 CrossRef CAS.
  7. M. E. Badding and F. J. DiSalvo, Inorg. Chem., 1990, 20, 3952 CrossRef.
  8. H. Womelsdorf and H.-J. Meyer, Angew. Chem., Int. Ed. Engl., 1994, 33, 1943 CrossRef.
  9. (a) A. Müller, Polyhedron, 1986, 5, 323 CrossRef; (b) R. H. Holm, Adv. Inorg. Chem., 1992, 38, 1 CrossRef CAS; (c) T. Saito, in Early Transition Metal Clusters with π-Donor Ligands, ed. M. H. Chisholm, VCH Publishers, New York, 1995, p. 63 Search PubMed; (d) I. Dance and K. Fisher, Prog. Inorg. Chem., 1994, 41, 637 CrossRef CAS; (e) T. Shibahara, Adv. Inorg. Chem., 1991, 37, 143 CrossRef CAS; (f) T. Shibahara, Coord. Chem. Rev., 1993, 123, 73 CrossRef CAS; (g) L. C. Roof and J. W. Kolis, Chem. Rev., 1993, 93, 1037 CrossRef CAS; (h) S. Harris, Polyhedron, 1989, 8, 2843 CrossRef CAS; (i) T. Saito, Adv. Inorg. Chem., 1996, 44, 45 CrossRef.
  10. V. E. Fedorov, A. V. Mishchenko and V. P. Fedin, Russ. Chem. Rev., 1985, 54, 408 CrossRef.
  11. (a) V. P. Fedin, I. V. Kalinina, A. V. Virovets, N. V. Podberezskaya and A. G. Sykes, Chem. Commun., 1998, 237 RSC; (b) V. P. Fedin, I. V. Kalinina, D. G. Samsonenko, Y. V. Mironov, M. M. Sokolov, S. V. Tkachev, A. V. Virovets, N. V. Podberezskaya, M. R. J. Elsegood, W. Clegg and A. G. Sykes, manuscript in preparation.
  12. (a) B. O. West, Polyhedron, 1989, 8, 219 CrossRef CAS and references therein; (b) J. Reim, K. Griesar, W. Haase and B. Krebs, J. Chem. Soc., Dalton. Trans., 1995, 2649 RSC; (c) H. Bock, H. tomDieck, H. Pyttlik and M. Schnöller, Z. Anorg. Allg. Chem., 1968, 357, 54 CrossRef CAS; (d) F. A. Cotton, X. Feng, P. A. Kibala and R. B. W. Sandor, J. Am. Chem. Soc., 1989, 111, 2148 CrossRef CAS.
  13. A. Müller, R. Jostes, W. Eltzner, C.-S. Nie, E. Diemann, H. Bögge, M. Zimmermann, M. Dartmann, U. Reinsh-Vogell, S. Che, S. J. Cyvin and B. N. Cyvin, Inorg. Chem., 1985, 24, 2872 CrossRef.
  14. B. Mach, H. Jacobs and W. Schäffer, Z. Anorg. Allg. Chem., 1987, 553, 187 CrossRef CAS.
  15. (a) A. Müller, E. Krichemeyer, H. Bögge, H. Ratajczak and A. Armatage, Angew. Chem., Int. Ed. Engl., 1994, 33, 770 CrossRef; (b) Y. V. Mironov, T. E. Albrecht-Schmitt and J. A. Ibers, Z. Kristallogr., New Cryst. Struct., 1997, 212, 308 CAS.
  16. M. Sokolov, A. Virovets, V. Nadolinnyi, K. Hegetschweiler, V. Fedin, N. Podberezskaya and V. Fedorov, Inorg. Chem., 1994, 33, 3503 CrossRef CAS.
  17. C. Mealli and D. M. Proserpio, J. Chem. Educ., 1990, 67, 399 CrossRef CAS.
  18. A. V. Mischenko, I. V. Yushina and V. E. Fedorov, Zh. Neorg. Khim., 1988, 33, 437 Search PubMed.
  19. G. M. Sheldrick, SHELX-97 Release 97-2, Göttingen University, Germany, 1997.