View PDF Version
 
DOI: 10.1039/A805899G (Paper) Reference Section for: Chem. Commun., 1998, 2083-2084

A novel polynuclear palladium(II) complex with asymmetric coordination of palladium atoms

(Note: The full text of this document is currently only available in the PDF Version )

Rong Cao, Weiping Su, Maochun Hong, Wenjian Zhang, Jiaxi Lu and Wing-Tak Wong

Abstract

The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(µ3-Se)2(µ-SCH2Ph)2(µ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.

References

  1. (a) M. J. H. Russel and C. F. J. Barnard, Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon, Oxford, 1987, vol. 5, p. 1103 Search PubMed; (b) A. L. Balch, Reactivity of Metal–Metal Bonds, ed. M. H. Chisholm, ACS Symp. Ser., 1981, 155, 167 Search PubMed.
  2. (a) R. J. Puddephatt, Chem. Soc. Rev., 1983, 12, 99 RSC; (b) R. Poilblanc, Coord. Chem. Rev., 1988, 86, 191 CrossRef CAS.
  3. A. L. Balch, in Homogeneous Catalysis with Metal Phosphine Complexes, ed. L. H. Pignolet, Plenum, New York, 1983, p. 167 Search PubMed.
  4. P. M. Maitlis, P. Espinet and M. J. H. Russel, Comprehensive Organometallic Chemistry, ed. G. Wilkinson, F. G. A. Stone and E. W. Abel, Pergamon, Oxford, 1982, vol. 6, p. 265 Search PubMed.
  5. (a) P. Braunstein, J.-M. Jud, Y. Dusausou and J. Fisher, Organometallics, 1983, 2, 180 CrossRef CAS; (b) P. Braunstein, J.-M. Jud, Y. Dusausou and J. Fisher, J. Chem. Soc., Chem. Commun., 1983, 5 RSC; (c) M. C. Grossel, R. P. Moulding and K. R. Seddon, J. Organomet. Chem., 1983, 253, C52 CrossRef CAS; (d) P. Braunstein, C. de Meric de Bellefon and M. Ries, ibid., 1984, 262, C14 Search PubMed; (e) P. Braunstein, J. Kervennal and J.-L. Richert, Angew. Chem., Int. Ed. Engl., 1985, 24, 768 CrossRef.
  6. (a) A. L. Balch, L. S. Benner and M. M. Olmstead, Inorg. Chem., 1979, 18, 2996 CrossRef CAS; (b) G. Besenyei, C. L. Lee, J. Gulinski, S. J. Retting, B. R. James, D. A. Nelson and M. A. Lilga, ibid., 1987, 26, 3622 Search PubMed; (c) G. Besenyei, L. Pàrkànyi, L. I. Simàndi and B. R. James, ibid., 1995, 34, 6118 Search PubMed.
  7. (a) R. Usón, J. Forniés, L. R. Falvello, I. Usón and S. Herrero, Inorg. Chem., 1993, 32, 1066 CrossRef CAS; (b) R. Usón, J. Forniés, S. Fernandez, M. A. Usón, I. Usón and S. Herrero, Inorg. Chem., 1997, 36, 1912 CrossRef CAS.
  8. (a) G. W. Wei, M. C. Hong, Z. Y. Huang and H. Q. Liu, J. Chem. Soc., Dalton Trans., 1991, 3145 RSC; (b) G. W. Wei, H. Q. Liu, Z. Y. Huang, M. C. Hong, L. R. Huang and B. S. Kang, Polyhedron, 1991, 10, 553 CrossRef CAS; (c) G. W. Wei, H. Q. Liu, Z. Y. Huang, L. R. Huang and B. S. Kang, J. Chem. Soc., Chem. Commun., 1989, 1839 RSC.
  9. (a) W. P. Su, M. C. Hong, Z. Y. Zhou, F. Xue, H. Q. Liu and T. C. W. Mak, Acta Crystallogr., Sect. C, 1996, 52, 2691 CrossRef; (b) W. P. Su, M. C. Hong, R. Cao and H. Q. Liu, Acta Crystallogr., Sect. C, 1997, 53, 66 CrossRef; (c) W. P. Su, R. Cao, M. C. Hong, Z. Y. Zhou, F. Xue, H. Q. Liu and T. C. W. Mak, Polyhedron, 1997, 16, 2531 CrossRef CAS.
  10. (a) R. Cao, M. C. Hong, F. L. Jiang and H. Q. Liu, Acta Crystallogr., Sect. C, 1995, 51, 1280 CrossRef; (b) R. Cao, Z. Y. Huang, X. J. Lei, M. C. Hong and H. Q. Liu, Chin. J. Chem., 1992, 10, 227 Search PubMed; (c) R. Cao, Z. Y. Huang, X. J. Lei, M. C. Hong and H. Q. Liu, Acta Crystallogr., Sect. C, 1992, 48, 1654 CrossRef.
  11. E. W. Abel, D. E. Evans, J. R. Koe, M. B. Hursthouse, M. Mazid, M. F. Mahon and K. C. Molloy, J. Chem. Soc., Dalton Trans., 1990, 1697 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.