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DOI: 10.1039/A805684F (Paper) Reference Section for: Chem. Commun., 1998, 2029-2030

Electrospray mass spectrometric studies of the rhenium hydroxy and methoxy carbonyl complexes [Re2(µ-OR)3(CO)6]– (R = H, Me)

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Chenghua Jiang and T. S. Andy Hor

Abstract

Exchange reactions of [Re2(µ-OR)3(CO)6]– (R = H, Me) with alcohols and phenol have been established by electrospray mass spectrometry (ESMS); dehydration of [Re2(µ-OH)3(CO)6]– and the β-hydride elimination reaction of [Re2(µ-OMe)3(CO)6]– have also been observed under ESMS conditions.

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