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DOI: 10.1039/A805443F (Paper) Reference Section for: Chem. Commun., 1998, 2131-2132

First of a new family of tetraamine bis(µ-thiolate)-containing macrocycles: structure and stepwise oxidations and reductions of the dinickel(II) complex

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Sally Brooker, Paul D. Croucher, Tony C. Davidson, Geoffrey S. Dunbar, A. James McQuillan and Geoffrey B. Jameson

Abstract

Reduction of a dinickel(II) dithiolate Schiff-base macrocyclic complex with sodium borohydride results in a ‘bowl’-shaped dinickel(II) dithiolate amine macrocyclic complex which exhibits four separate one-electron redox processes.

References

  1. A. Volbeda, M.-H. Charon, C. Piras, E. C. Hatchikian, M. Frey and J. C. Fontecilla-Camps, Nature, 1995, 373, 580 CrossRef CAS.
  2. See for example: A. F. Kolodziej, Prog. Inorg. Chem., 1994, 41, 493 Search PubMed; M. A. Halcrow and G. Christou, Chem. Rev., 1994, 94, 2421 CAS; C. M. Goldman and P. K. Mascharak, Comments Inorg. Chem., 1995, 18, 1 CrossRef CAS; J. C. Fontecilla, J. Biol. Inorg. Chem., 1996, 91 CAS; M. Frey, Struct. Bonding, 1998, 90, 97 CrossRef CAS.
  3. C. A. Marganian, H. Vazir, N. Baidya, M. M. Olmstead and P. K. Mascharak, J. Am. Chem. Soc., 1995, 117, 1584 CrossRef CAS.
  4. See for example: G. Musie, P. J. Farmer, T. Tuntulani, J. H. Reibenspies and M. Y. Darensbourg, Inorg. Chem., 1996, 35, 2176 Search PubMed; C.-H. Lai, J. H. Reibenspies and M. Y. Darensbourg, Angew. Chem., Int. Ed. Engl., 1996, 35, 2390 CrossRef.
  5. S. Brooker and P. D. Croucher, J. Chem. Soc., Chem. Commun., 1995, 1493; 2075 RSC; Chem. Commun., 1997, 459 Search PubMed; S. Brooker and T. C. Davidson, Chem. Commun., 1997, 2007 Search PubMed.
  6. S. Brooker, P. D. Croucher and F. M. Roxburgh, J. Chem. Soc., Dalton Trans., 1996, 3031 RSC.
  7. S. Brooker, P. D. Croucher, T. C. Davidson, G. S. Dunbar, P. D. Smith, S. P. Cramer, C. Y. Ralston, C. Coates, J. J. McGarvey, C. Beck and S. Subramanian, unpublished results.
  8. See for example: A. M. Bond, M. Haga, I. S. Creece, R. Robson and J. C. Wilson, Inorg. Chem., 1988, 27, 712 Search PubMed; G. A. Lawrance, M. Maeda, T. M. Manning, M. A. O'Leary, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 1990, 2491 CrossRef CAS; N. D. J. Branscombe, A. J. Blake, A. Marin-Becerra, W.-S. Li, S. Parsons, L. Ruiz-Ramirez and M. Schröder, Chem. Commun., 1996, 2573 RSC.
  9. N. F. Curtis, J. Chem. Soc. A., 1965, 925 Search PubMed.
  10. F. V. Lovecchio, E. S. Gore and D. H. Busch, J. Am. Chem. Soc., 1974, 96, 3109 CrossRef CAS; A. G. Lappin and A. McAuley, Adv. Inorg. Chem., 1988, 32, 241 CAS; T. Yamamura, M. Tadokoro, K. Tanaka and R. Kuroda, Bull. Chem. Soc. Jpn., 1993, 66, 1984 CAS.
  11. ‘Green energy’, see for example: T. Newton, Chem. in Brit., 1997, January, 29 Search PubMed; J. C. Fontecilla-Camps, A. Volbeda and M. Frey, Trends Biotechnol., 1996, 14, 417 Search PubMed; A. Coghlan, New Scientist,, 1996, January, 14 CrossRef CAS; L. L. Efros, H. H. Thorp, G. W. Brudvig and R. H. Crabtree, Inorg. Chem., 1992, 31, 1722 Search PubMed.
  12. G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467 CrossRef.
  13. G. M. Sheldrick, manuscript in preparation.
  14. R. Greef, R. Peat, L. M. Peter, D. Pletcher and J. Robinson, Instrumental Methods in Electrochemistry, Ellis Horwood, UK, 1985, ch. 6, p. 178 Search PubMed.
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