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DOI: 10.1039/A805410J (Paper) Reference Section for: Chem. Commun., 1998, 2219-2220

Infinite linear chains of Sb atoms in the novel metal-rich polyantimonides Zr7.5V5.5Sb10 and Zr6.5V6.5Sb10

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Holger Kleinke

Abstract

The structures of the title compounds exhibit short Sb–Sb bonds besides a multitude of bonding M–M interactions, i.e. the M atoms (Zr and V) in low valent states.

References

  1. J.-M. Rouxel, Chem. Eur. J., 1996, 2, 1053 CAS.
  2. L. H. Brixner, J. Inorg. Nucl. Chem., 1960, 15, 199 CrossRef CAS.
  3. B. Frick, J. Schoenes, F. Hulliger and O. Vogt, Solid State Commun., 1984, 49, 1133 CrossRef CAS.
  4. H. Nowotny and J. Peal, Monatsh. Chem., 1951, 82, 336 CAS.
  5. J. Bouwma, C. F. van Bruggen and C. Haas, J. Solid State Chem., 1973, 7, 255 CrossRef CAS.
  6. L. F. Myzenkova, V. V. Baron and Y. M. Savitsky, Russ. Metall. (transl. Izvest. Akad. Nauk SSR, Met.), 1966, 2, 89 Search PubMed.
  7. E. Garcia and J. D. Corbett, J. Solid State Chem., 1988, 73, 452 CrossRef CAS.
  8. R. L. Abdon and T. Hughbanks, J. Am. Chem. Soc., 1995, 117, 10 035 CrossRef CAS.
  9. H. Kleinke and H. F. Franzen, J. Alloys Compd., 1998, 266, 139 CrossRef CAS.
  10. Crystal data(IPDS, Stoe, T = 293 K): Zr7.5V5.5Sb10: M= 2182 orthorhombic, space group Pnma; a= 1871.6(2), b= 567.22(6), c= 1764.9(2) pm; Z= 4, µ= 20.7 mm–1 , 2681 independent reflections; R(F)= 0.036, Rw(F2)= 0.074 for 1069 observed reflections [I > 2σ(I)]. Zr6.5V6.5Sb10: M= 2142 orthorhombic, space group Pnma, a= 1866.7(3), b= 569.09(7), c= 1753.7(2) pm, Z= 4, µ= 20.7 mm–1, 2433 independent reflections; R(F)= 0.060, Rw(F2)= 0.111 for 575 observed reflections [I > 2σ(I)]. CCDC 182/1007.
  11. D. Eberle and K. Schubert, Z. Metallk., 1968, 59, 306 Search PubMed.
  12. L. Pauling, The Nature of the Chemical Bond, Cornell University Press, Ithaca, NY, 3rd edn., 1948 Search PubMed.
  13. H. Kleinke and H. F. Franzen, J. Am. Chem. Soc., 1997, 119, 12 824 CrossRef CAS.
  14. M. Köckerling and H. F. Franzen, Croat. Chem. Acta, 1995, 68, 709 Search PubMed.
  15. H. Kleinke, Eur. J. Inorg. Chem., 1998, 9, 1369 CrossRef.
  16. W. Hönle and H.-G. von Schnering, Z. Kristallogr., 1981, 155, 307.
  17. N. Korber and F. Richter, Angew. Chem., 1997, 109, 1575.
  18. U. Bolle and W. Tremel, J. Chem. Soc., Chem. Commun., 1992, 91 RSC.
  19. R. Hoffmann, J. Chem. Phys., 1963, 39, 1397 CrossRef CAS; Program EHMACC, adapted for use on a PC by M. Köckerling, Gesamthochschule Duisburg, 1997.
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