View PDF Version
 
DOI: 10.1039/A805397I (Paper) Reference Section for: Chem. Commun., 1998, 2109-2110

Deep cavity [CpFe(arene)]+ derivatized cyclotriveratrylenes as anion hosts

(Note: The full text of this document is currently only available in the PDF Version )

K. Travis Holman, G. William Orr, Jerry L. Atwood and Jonathan W. Steed

Abstract

Even in the absence of hydrogen bonding functionality, [CpFe(arene)]+ derivatized cyclotriveratrylenes 5 will bind anionic substrates (i.e. [PF6]–, halides) deep within their preorganized molecular cavities. The crystal structure of 5b[PF6]3·(CH3CH2OCH2CH3)1.5·(H2O) demonstrates the [5b⊂(PF6)]2+ complex and solution halide binding is monitored by 1H NMR spectroscopy.

References

  1. (a) C. Seel and J. de Mendoza, Comprehensive Supramolecular Chemistry, ed. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle, Elsevier, New York, 1996, vol. 2, ch. 17, pp. 519–552 Search PubMed; (b) Supramolecular Chemistry of Anions, ed. A. Bianchi, K. Bowman-James and E. García-España, Wiley-VCH, New York, 1997 Search PubMed; (c) K. T. Holman, J. L. Atwood and J. W. Steed, Advances in Supramolecular Chemistry, ed. G. W. Gokel, JAI Press, Greenwich, CT, 1997, vol. 4, ch. 7, pp. 287–330 Search PubMed.
  2. (a) K. T. Holman, M. M. Halihan, J. W. Steed, S. S. Jurisson and J. L. Atwood, J. Am. Chem. Soc., 1995, 117, 7848 CrossRef CAS; (b) J. L. Atwood, K. T. Holman and J. W. Steed, Chem. Commun., 1996, 1401 RSC; (c) K. T. Holman, M. M. Halihan, S. S. Jurisson, J. L. Atwood, R. S. Burkhalter, A. R. Mitchell and J. W. Steed, J. Am. Chem. Soc., 1996, 118, 9567 CrossRef CAS; (d) M. Staffilani, K. S. B. Hancock, J. W. Steed, K. T. Holman, J. L. Atwood, R. K. Juneja and R. S. Burkhalter, J. Am. Chem. Soc., 1997, 119, 6324 CrossRef CAS; (e) M. Staffilani, G. Bonvicini, J. W. Steed, K. T. Holman, J. L. Atwood and M. R. J. Elsegood, Organometallics, 1998, 17, 1732 CrossRef CAS.
  3. (a) P. D. Beer, Chem Commun., 1996, 689 RSC and references therein; (b) P. D. Beer, Acc. Chem. Res., 1998, 31, 71 CrossRef CAS and references therein; (c) P. D. Beer, C. A. P. Dickson, N. Fletcher, A. J. Goulden, J. Hodacova and T. Wear, J. Chem. Soc., Chem. Commun., 1993, 828 RSC.
  4. J. Canceill, A. Collet, J. Gabard, G. Gotarelli and G. P. Spada, J. Am. Chem. Soc., 1985, 107, 1299 CrossRef CAS.
  5. For general methods, see: A. S. Abd-El-Aziz, C. R. de Denus, M. J. Zaworotko and L. R. MacGillivray, J. Chem. Soc., Dalton Trans., 1995, 3375 Search PubMed.
  6. A. Collet, Comprehensive Supramolecular Chemistry, ed. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle, Elsevier, New York, 1996, vol. 2, ch. 11, pp. 325–365 Search PubMed.
  7. L. J. Barbour and J. L. Atwood, J. Appl. Crystallogr., 1998, in press Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.