New sulfide-bridged heterocubanes [M^VI(S)Re^I₃(CO)₉(µ₃-S)₄]^–, M = Mo or W, with transition metals in very different oxidation states

Abstract

The cluster anions [M^VI(S)Re^I₃(CO)₉(µ₃-S)₄]^–, M = Mo or W, contain three six-coordinate tricarbonylrhenium(I) fragments, held together by one µ₃-sulfide ion and by one reducible and charge transfer-active µ₃-M^VIS₄^2– unit.

References

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