An osmium nitrido complex as a π-acid ligand for late transition metals
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Thomas J. Crevier, Scott Lovell and James M. Mayer
Abstract
The Os(VI) nitrido complex, TpOs(N)Cl2 (1), acts as a π-acid ligand in the cobalt and platinum complexes CpCo[NOs(Tp)Cl2]2 (2) and (Me2S)Cl2Pt–NOs(Tp)Cl2 (3).
References
(a) K. Dehnicke and J. Strahle, Angew. Chem., Int. Ed. Engl., 1992, 31, 955 CrossRef;
(b) W. A. Nugent and
J. M. Mayer,
Metal Ligand Multiple Bonds,
Wiley-Interscience,
1988 Search PubMed.
(a) N. M. Doherty and S. C. Critchlow, J. Am. Chem. Soc., 1987, 109, 7906 CrossRefCAS;
(b) C. M. Jones and N. M. Doherty, Polyhedron, 1995, 14, 81 CrossRefCAS and references therein;
(c) R. W. Marshman, J. M. Shusta, S. R. Wilson and P. A. Shapley, Organometallics, 1991, 10, 1671 CrossRefCAS;
(d) J. Chatt and B. T. Heaton, Chem. Commun., 1968, 274 RSC.
(a) T. J. Crevier and J. M. Mayer, J. Am. Chem. Soc., 1998, 120, 5595 CrossRefCAS;
(b) T. J. Crevier and J. M. Mayer, Angew. Chem., Int. Ed. Engl., 1998, 37, 1891 CrossRefCAS;
(c) T. J. Crevier, PhD Thesis, University of Washington,
1998.
For leading references, see:
(a) A. J. DelMonte, J. Haller, K. N. Houk, K. B. Sharpless, D. A. Singleton, T. Strassner and A. A. Thomas, J. Am. Chem. Soc., 1997, 119, 9907 CrossRefCAS;
(b) J. Du Bois, C. S. Tomooka, J. Hong and E. M. Carreira, Acc. Chem. Res., 1997, 30, 364 CrossRefCAS;
(c) S. N. Brown and J. M. Mayer, J. Am. Chem. Soc., 1996, 118, 12119 CrossRefCAS.
Prepared from Cp2Co and C6F5I.
B. K. Bennett, PhD Thesis, University of Utah, Salt Lake City, Utah,
1997.
L. R. Byers and L. F. Dahl, Inorg. Chem., 1980, 19, 277 CrossRefCAS.
From the Cambridge Structure Database (January, 1998): F. H. Allen and O. Kennard, Chem. Des. Automat. News, 1993, 8, 31 Search PubMed.
(a) Comprehensive Organometallic Chemistry, ed.
G. Wilkinson,
Pergamon,
New York,
1982, vol. 5,
pp. 1–276 Search PubMed;
(b) Comprehensive Organometallic Chemistry II, ed.
G. Wilkinson,
Pergamon,
New York,
1995, vol. 8,
pp. 1–114 Search PubMed.
R. F. Heck, Inorg. Chem., 1968, 7, 1513 CrossRefCAS may report a rare exception.
W.-H. Leung, J. L. C. Chim and W.-T. Wong, J. Chem. Soc., Dalton Trans., 1996, 3153 RSC; 1997,
3277.
D. Hrovat,
T. J. Crevier,
W. T. Borden and
J. M. Mayer, work in progress.
J. L. Koch and P. A. Shapley, Organometallics, 1997, 16, 4071 CrossRef.
J. E. Huheey,
Inorganic Chemistry,
Harper & Row,
New York, 3rd edn.,
1983,
pp. 73, 75 Search PubMed.
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