An osmium nitrido complex as a π-acid ligand for late transition metals

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Thomas J. Crevier, Scott Lovell and James M. Mayer


Abstract

The Os(VI) nitrido complex, TpOs(N)Cl2 (1), acts as a π-acid ligand in the cobalt and platinum complexes CpCo[NOs(Tp)Cl2]2 (2) and (Me2S)Cl2Pt–N[triple bond, length half m-dash]Os(Tp)Cl2 (3).


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