DOI: 10.1039/A805034A
(Paper)
Reference Section for: Chem. Commun., 1998, 2425-2426
Cyclopentadienyl titanium chlorides containing ortho-(1-naphthyl)phenoxide ligation
(Note: The full text of this document is currently only available in the PDF Version )
Jonathan S. Vilardo, Matthew G. Thorn, Phillip E. Fanwick and Ian P. Rothwell
Abstract
A series of mono-cyclopentadiene derivatives of titanium containing ortho-(1-naphthyl)phenoxide ligands have been studied; the Ti–Ti distance in the d1–d1 species [Cp(ArO)Ti(µ-Cl)2Ti(OAr)Cp] is exactly intermediate between that found in paramagnetic [Cp2Ti(µ-Cl)2TiCp2] and diamagnetic [(ArO)2Ti(µ-Cl)2Ti(OAr)2].
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