A tailor-made hexagonal system in a molecular conductor

(Note: The full text of this document is currently only available in the PDF Version )

Tatsuro Imakubo, Takahisa Maruyama, Keiji Kobayashi and Hiroshi Sawa


Abstract

A unique hexagonal system based on an organic π-donor has been tailored by the strong and directional I···N intermolecular interaction, and its highly symmetrical structure including two types of channels and high conductivity are reported.


References

  1. For recent progress of molecular conductors, see Z. V. Vardeny and A. J. Epstein, ed., Synth. Met., 1997, 86 Search PubMed (the latest proceedings of the international conference on science and technology of synthetic metals, ICSM'96).
  2. For recent progress of fullerenes, see H. W. Kroto, J. E. Fischer and D. E. Cox, The Fullerenes, Pergamon, Oxford, 1993 Search PubMed; Acc. Chem. Res.(special issue on buckminsterfullerenes), 1992, 25, 97 Search PubMed.
  3. (a) G. R. Desiraju, Crystal engineering: the design of organic solids, Elsevier, Amsterdam, 1989 Search PubMed; (b) G. R. Desiraju, Angew. Chem., Int. Ed. Engl., 1995, 34, 2311 CrossRef CAS and references therein.
  4. (a) T. Imakubo, H. Sawa and R. Kato, Synth. Met., 1995, 73, 117 CrossRef CAS; (b) T. Imakubo, H. Sawa and R. Kato, J. Chem. Soc., Chem. Commun., 1995, 1097 RSC; (c) T. Imakubo, H. Sawa and R. Kato, J. Chem. Soc., Chem. Commun., 1995, 1668 Search PubMed; (d) T. Imakubo, H. Sawa and R. Kato, Mol. Cryst. Liq. Cryst., 1996, 285, 27 Search PubMed.
  5. (a) E. O. Schlemper and D. Britton, Acta Crystallogr., 1965, 18, 419 CrossRef CAS; (b) G. R. Desiraju and R. L. Harlow, J. Am. Chem. Soc., 1989, 111, 6757 CrossRef CAS.
  6. (a) R. Gompper, J. Hock, K. Polborn, E. Dormann and H. Winter, Adv. Mater., 1995, 7, 41 CrossRef CAS; (b) T. Imakubo, H. Sawa and R. Kato, Synth. Met., 1997, 86, 1883 CrossRef CAS.
  7. G. C. Papavassiliou, S. Y. Yiannopoulos, J. S. Zambounis, K. Kobayashi and K. Umemoto, Chem. Lett., 1987, 1279 CAS.
  8. A. Bondi, J. Phys. Chem., 1964, 68, 441 CrossRef CAS.
  9. W. M. Meier and D. H. Olson, Atlas of zeolite structure types, Butterworth-Heinemann, London, 1992 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.