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DOI: 10.1039/A804702B (Paper) Reference Section for: Chem. Commun., 1998, 1891-1892

Enantioselective sulfoxidation mediated by vanadium-incorporated phytase: a hydrolase acting as a peroxidase

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Fred van de Velde and Lars Könemann

Abstract

Phytase (E.C. 3.1.3.8), which in vivo mediates the hydrolysis of phosphate esters, catalyses the enantioselective oxidation of thioanisole with H2O2, both in the presence and absence of vanadate ion, affording the S-sulfoxide in up to 66% ee at 100% conversion.

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