Hydrothermal synthesis and structure of a three-dimensional open-framework cobalt molybdenum(VI) phosphate containing ethylenediammonium ions: (C₂H₉N₂)₆[Co₃Mo₄P₄O₂₈]

Abstract

The first microporous cobalt molybdenum(VI) phosphate, crystallised under hydrothermal conditions, is constructed from unique CoMo₂P tetrahedral units connected by CoO₄ tetrahedra and by sharing corners; the framework contains interlocking cavity units and unusual 7-ring intersecting channels that are filled with charge-compensating ethylenediammonium ions.

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