View PDF Version
 
DOI: 10.1039/A803760D (Paper) Reference Section for: Chem. Commun., 1998, 1753-1754

A new structural type in iron carboxylate cluster chemistry via use of bis-bipyridine ligands: [Fe6O4Cl4(O2CPh)4L2][FeCl4]2

(Note: The full text of this document is currently only available in the PDF Version )

Craig M. Grant, John C. Huffman, George Christou, Michael J. Knapp, John C. Huffman and David N. Hendrickson

Abstract

The reaction between FeCl3, NaO2CPh and L [L = 1,2-bis(2,2′-bipyridyl-6-yl)ethane] in MeCN gives the title complex 1 whose cation contains an unusual [Fe6(µ3-O)4]10+ core, whereas in MeOH the dinuclear complex [Fe2(OMe)2Cl2(O2CPh)L][FeCl4] 2 is obtained; magnetic studies indicate that the cations of 1 and 2 both have S = 0 ground states, consistent with the expected antiferromagnetic exchange interactions.

References

  1. R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1993, 115, 1804 CrossRef CAS; R. Sessoli, D. Gatteschi, A. Caneschi and M. Novak, Nature, 1993, 365, 141 CrossRef CAS.
  2. H. J. Eppley, H.-L. Tsai, N. Devries, K. Folting, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1995, 117, 301 CrossRef CAS; S. M. J. Aubin, S. Spagna, H. J. Eppley, R. E. Sager, G. Christou and D. N. Hendrickson, Chem. Commun., 1998, 803 RSC.
  3. S. M. J. Aubin, H. J. Eppley, I. A. Guzei, K. Folting, P. K. Grantzel, A. L. Rheingold, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1998, submitted for publication Search PubMed.
  4. S. M. J. Aubin, M. W. Wemple, D. M. Adams, H.-L. Tsai, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1996, 118, 7746 CrossRef CAS.
  5. S. K. J. Aubin, N. R. Dilley, L. Pardi, J. Krzystek, M. W. Wemple, L.-C. Brunel, M. B. Maple, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1998, 120, 4991 CrossRef CAS.
  6. Z. Sun, C. M. Grant, S. L. Castro, D. N. Hendrickson and G. Christou, Chem. Commun., 1998, 721 RSC; S. L. Castro, Z. Sun, C. M. Grant, J. C. Bollinger, D. N. Hendrickson and G. Christou, J. Am. Chem. Soc., 1998, 120, 2365 CrossRef CAS.
  7. A.-L. Barra, P. Debrunner, D. Gatteschi, C. E. Schulz and R. Sessoli, Europhys. Lett., 1996, 35, 133 Search PubMed.
  8. J. K. McCusker, J. B. Vincent, E. A. Schmitt, M. L. Mino, K. Shin, D. K. Coggin, P. M. Hagen, J. C. Huffman, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1991, 113, 3012 CrossRef CAS.
  9. S. M. Gorun and S. J. Lippard, Inorg. Chem., 1991, 30, 1625 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.