The effect of substitution of the C–F group for the C–H group in crystal packing as well as thermal behaviour

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Naoto Hayashi and Takashi Mori


Abstract

The packing motif and/or thermal stability of a crystal is controlled by intermolecular C–F···π interactions.


References

  1. K. Vishnumurthy, T. N. G. Row and K. Venkantesan, J. Chem. Soc., Perkin Trans. 2, 1996, 1475 RSC; K. Vishnumurthy, T. N. G. Row and K. Venkatesan, J. Chem. Soc., Perkin Trans. 2, 1997, 615 RSC.
  2. T. Hasegawa, K. Inukai, S. Kagoshima, T. Sugawara, T. Mochida, S. Sugiura and Y. Iwasa, Chem. Commun., 1997, 1377 RSC.
  3. G. W. Chates, A. R. Dunn., L. M. Henling, D. A. Dougherty and R. H. Grubbs, Angew. Chem., Int. Ed. Engl., 1997, 36, 248 CrossRef CAS; G. W. Chates, A. R. Dunn., L. M. Henling, J. W. Ziller, E. B. Lobkovsky and R. H. Grubbs, J. Am. Chem. Soc., 1998, 120, 3641 CrossRef CAS.
  4. Although the inclusion properties of triphenylmethanol, X-ray crystal structure and thermal release of the guest component of its methanol clathrate have been reported (ref. 5), we performed DSC analysis and a reexamination of the X-ray diffraction study (not shown) of it here for comparison.
  5. E. Weber, K. Skobridis and I. Goldberg, J. Chem. Soc., Chem. Commun., 1989, 1195 RSC.
  6. J. D. Dunitz and R. Taylor, Chem. Eur. J., 1997, 3, 89 CrossRef CAS.
  7. J. L. Atwood, S. G. Bott, C. James and C. L. Raston, J. Chem. Soc., Chem. Commun., 1992, 1349 RSC; J. L. Atwood, F. Hamada, K. D. Robinson, G. W. Orr and R. L. Vincent, Nature, 1991, 349, 683 CrossRef CAS; S. Apel, M. Czugler, V. J. Griffith, L. R. Nassimbeni and E. Weber, J. Chem. Soc., Perkin Trans. 2, 1997, 1949 RSC; T. Steiner and W. Saenger, J. Chem. Soc., Chem. Commun., 1995, 2087 RSC; M. Nishio, M. Hirota and Y. Umezawa, The CH/π Interaction. Evidence, Nature and Consequences, Wiley, New York, 1998 Search PubMed.
  8. A. Bondi, J. Phys. Chem., 1964, 68, 441 CrossRef CAS.
  9. TeXsan, Crystal Structure Analysis Package, Molecular Structure Corporation, 1992.
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