DOI: 10.1039/A803485K
(Paper)
Reference Section for: Chem. Commun., 1998, 1565-1566
A convenient synthesis of the cruciferous phytoalexins brassicanal A and brassilexin by mimicry of a fungal detoxification pathway
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M. Soledade C. Pedras
Abstract
The cruciferous phytoalexin brassilexin 3 has been synthesized in four steps from indoline-2-thione via 3-(aminomethylene)indole-2-thione 2, a metabolic intermediate of the detoxification pathway of the phytoalexin cyclobrassinin 1; in addition, the phytoalexin brassicanal A 8 has been synthesized in two steps from 2-indolinethione.
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