Cationic allenylidene ruthenium complexes [Ru![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CCCR2(L)(Cl)(arene)]PF6 (L = PCy3, PPri3), easily prepared from RuCl2(L)(p-cymene), prop-2-yn-1-ol and NaPF6, are found to be excellent catalyst precursors for ring closing olefin metathesis.
A. Fürstner, A. Fürstner, M. Picquet, C. Bruneau and P. H. Dixneuf, Chem. Commun., 1998, 1315 DOI: 10.1039/A803286F
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