DOI: 10.1039/A802658K
(Paper)
Reference Section for: Chem. Commun., 1998, 1653-1654
Intramolecular macrocyclization of bis(5-methylthio-1,2-dithiole-3-thione)s with triethyl phosphite. A stereoselective route to macrocyclic (Z)-thioxodesaurines
(Note: The full text of this document is currently only available in the PDF Version )
Sandra Rudershausen, Hans-Jürgen Holdt, Helmut Reinke, Hans-Joachim Drexler, Joachim Teller and Manfred Michalik
Abstract
Intramolecular macrocyclizations of [oligo(oxyethylene)ethylenedithio]bridged bis(5-methylthio-1,2-dithiole-3- thione)s 5a and b with P(OEt)3 in p-xylene furnished the macrocyclic thioxodesaurin (Z)-6, thioxodesaurin (E)-7 and 1,3-dithiafulvene (E)-8, respectively.
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