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DOI: 10.1039/A802548G (Paper) Reference Section for: Chem. Commun., 1998, 1491-1492

Synthesis and characterization of [NBu4]4[Ag2{Mo5O13(OMe)4(NO)}2], a novel polyoxomolybdate complex with a short AgI···AgI distance

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Richard Villanneau, Anna Proust and Francis Robert

Abstract

In methanol, the defect nitrosylpolyoxomolybdate [Mo5O13(OMe)4(NO)]3– reacts with Ag+ to give the complex [Ag2{Mo5O13(OMe)4(NO)}2]4– which displays attractive interactions between the two square-planar closed-shell AgI cations.

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