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DOI: 10.1039/A802351D (Paper) Reference Section for: Chem. Commun., 1998, 1231-1232

Molecular Prussian Blue analogues: synthesis and structure of cubic Cr4Co4(CN)12 and Co8(CN)12 clusters

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Julie L. Heinrich, Polly A. Berseth and Jeffrey R. Long

Abstract

Reactions between [M(H2O)3(tacn)]3+ (M = Cr, Co) and [Co(CN)3(tacn)] are demonstrated to produce the molecular box clusters [Cr4Co4(CN)12(tacn)8]12+ and [Co8(CN)12- (tacn)8]12+ with core structures consisting of a single cubic unit excised from the Prussian Blue type framework.

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