View PDF Version
 
DOI: 10.1039/A802351D (Paper) Reference Section for: Chem. Commun., 1998, 1231-1232

Molecular Prussian Blue analogues: synthesis and structure of cubic Cr4Co4(CN)12 and Co8(CN)12 clusters

(Note: The full text of this document is currently only available in the PDF Version )

Julie L. Heinrich, Polly A. Berseth and Jeffrey R. Long

Abstract

Reactions between [M(H2O)3(tacn)]3+ (M = Cr, Co) and [Co(CN)3(tacn)] are demonstrated to produce the molecular box clusters [Cr4Co4(CN)12(tacn)8]12+ and [Co8(CN)12- (tacn)8]12+ with core structures consisting of a single cubic unit excised from the Prussian Blue type framework.

References

  1. D. F. Shriver, S. A. Shriver and S. E. Anderson, Inorg. Chem., 1965, 4, 725 CrossRef CAS .
  2. K. R. Dunbar and R. A. Heintz, Prog. Inorg. Chem., 1997, 45, 283 CAS  and references therein.
  3. G. B. Seifer, Russ. J. Inorg. Chem., 1959, 4, 841 .
  4. C. Loos-Neskovic, M. Fedoroff and E. Garnier, Talanta, 1989, 36, 749 CrossRef CAS .
  5. J. Kuyper and G. Boxhoorn, J. Catal., 1987, 105, 163 CrossRef CAS .
  6. V. Gadet, T. Mallah, I. Castro and M. Verdageur, J. Am. Chem. Soc., 1992, 114, 9213 CrossRef CAS .
  7. T. Mallah, S. Thiébaut, M. Verdaguer and P. Veillet, Science, 1993, 262, 1554 CrossRef CAS .
  8. W. R. Entley and G. S. Girolami, Science, 1995, 268, 397 CrossRef CAS .
  9. S. Ferlay, T. Mallah, R. Ouahès, P. Veillet and M. Verdaguer, Nature, 1995, 378, 701 CrossRef CAS .
  10. O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 1996, 271, 49 CrossRef CAS .
  11. O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 1996, 272, 704 CrossRef CAS .
  12. C. K. Ryu, R. B. Lessard, D. Lynch and J. F. Endicott, J. Phys. Chem., 1989, 93, 1752 CrossRef CAS .
  13. F. Galsbøl, C. H. Petersen and K. Simonsen, Acta Chem. Scand., 1996, 50, 567 .
  14. J.-F. Bertrán, J. B. Pascual and E. R. Ruiz, Spectrochim. Acta, Part A, 1990, 46, 685 CrossRef .
  15. K. K. Klausmeyer and T. B. Rauchfuss, in Abstracts from the 215th National Meeting of the American Chemical Society: Division of Inorganic Chemistry, abstract no. 478 Search PubMed .
  16. H. J. Buser, D. Schwarzenbach, W. Petter and A. Ludi, Inorg. Chem., 1977, 16, 2704 CrossRef CAS .
  17. A. Ludi and H. U. Güdel, Helv. Chim. Acta, 1968, 51, 2006 CrossRef CAS .
  18. R. F. Phillips and H. M. Powell, Proc. R. Soc. London Ser. A, 1939, 173, 147 .
  19. P. J. Stang and B. Ogdan, Acc. Chem. Res., 1997, 30, 502 CrossRef CAS  and references therein.
Click here to see how this site uses Cookies. View our privacy policy here.