DOI: 10.1039/A802171F
(Paper)
Reference Section for: Chem. Commun., 1998, 1309-1310
Remarkable effects of side-chain alkyl substituents on thermochromic behavior of peralkyldecasilanes
(Note: The full text of this document is currently only available in the PDF Version )
Kuninori Obata, Mitsuo Kira, Kuninori Obata and Mitsuo Kira
Abstract
The absorption spectrum of perhexyldecasilane shows marked temperature dependence; a two-site model, similar to the transition from a random coil to an all pseudo-trans rod conformation proposed for poly(dihexylsilylene), is proposed to explain this effect.
References
- For reviews, see: R. D. Miller and J. Michl, Chem. Rev., 1989, 89, 1359 Search PubMed; J. Michl, J. W. Downing, T. Karatsu, A. J. McKinley, G. Poggi, G. M. Wallraff, R. Sooriyakumaran and R. D. Miller, Pure Appl. Chem., 1988, 60, 959 CrossRef CAS; J. M. Zeigler, Synth. Met., 1989, 28, C581 CAS; R. West, J. Organomet. Chem., 1986, 300, 327 CAS; R. West, in The Chemistry of Organosilicon Compounds, ed. S. Patai and Z. Rappoport, Wiley, Chichester, 1989, ch. 19, p. 1207 CrossRef CAS.
- (a) L. A. Harrah and J. M. Zeigler, J. Poly. Sci., Polym. Lett. Ed., 1985, 23, 209 Search PubMed; (b) P. Trefonas, III, J. R. Damewood, Jr., R. West and R. D. Miller, Organometallics, 1985, 4, 1318 CrossRef.
- R. D. Miller, G. M. Wallraff, M. Baier, P. M. Cotts, P. Shukla, T. P. Russel, F. C. Schryver and D. Declercq, J. Inorg. Organomet. Polym., 1991, 1, 505 CrossRef CAS; P. Hukla, P. M. Cotts, R. D. Miller, T. P. Russel, O. A. Smith, G. M. Wallraff, M. Baier and P. Thiyagarajan, Macromolecules, 1991, 24, 5606 CrossRef.
- (a) Y.-P. Sun and J. Michl, J. Am. Chem. Soc., 1992, 114, 8186 Search PubMed and references cited therein.
- K. Obata, C. Kabuto and M. Kira, J. Am. Chem. Soc., 1997, 119, 11 345 CrossRef CAS.
- M. Kumada and K. Tamao, Adv. Organomet. Chem., 1968, 6, 19 CAS.
- M. R. Frierson, M. R. Imam, V. B. Zalkow and N. L. Allinger, J. Org. Chem., 1988, 53, 5248 CrossRef.