Electrochemical–hydrothermal synthesis and structure determination of a novel layered mixed-valence oxide: BaV₇O₁₆·nH₂O

Abstract

The electrochemical–hydrothermal synthesis of a new mixed-valence oxide BaV₇O₁₆·nH₂O (n ≈ 4.4) with [V₇O₁₆] layers containing both vanadium oxygen tetrahedra and distorted octahedra is reported.

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