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DOI: 10.1039/A801936C (Paper) Reference Section for: Chem. Commun., 1998, 1373-1374

First uranium(IV) triflates

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Jean Claude Berthet, Michel Ephritikhine, Jean Claude Berthet, Monique Lance and Martine Nierlich

Abstract

The uranium(IV) triflates [U(Cp*)2(OTf)2], [U(Cp)2-(OTf)2(py)], [U(Cp)3(OTf)], [U(cot)(OTf)2(py)] and [U(OTf)4(py)] have been synthesized by protonation of amide or alkyl precursors with pyridinium triflate; the crystal structures of [U(Cp*)2(OTf)2(OH2)] and [U(Cp)3-(OTf)(CNBut)] have been determined.

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