View PDF Version
 
DOI: 10.1039/A801863D (Paper) Reference Section for: Chem. Commun., 1998, 1375-1376

A remarkable example of co-crystallisation: the crystal structure of the mononuclear and dinuclear diphenyl[2.2]paracyclophanylphosphine palladium(II) chloride complexes trans-[Pd{PPh2(C16H15)}2Cl2]·[Pd{PPh2(C16H15)}Cl2]2·0.6CH2Cl2

(Note: The full text of this document is currently only available in the PDF Version )

Philip W. Dyer, Paul J. Dyson, Stuart L. James, Priya Suman, Philip W. Dyer, John E. Davies and Caroline M. Martin

Abstract

The reaction of [Pd(cod)Cl2] (cod = cycloocta-1,5-diene) with rac-diphenyl[2.2]paracyclophanylphosphine PPh2(C16H15) affords trans-[Pd{PPh2(C16H15)}2Cl2] and [Pd{PPh2(C16H15)}Cl2]2 in approximately equal yield which co-crystallise to form an unusual solid-state material.

References

  1. A. I. Kitaigorodsky, in Mixed Crystals, ed. M. Cardona, Solid State Sciences, vol. 33, Springer-Verlag, Berlin, 1984 Search PubMed; G. R. Desiraju, Crystal Engineering. The Design of Organic Solids, Elsevier, Amsterdam, 1989 Search PubMed.
  2. See, for example: D. Braga, F. Grepioni, P. Milne and E. Parasini, J. Am. Chem. Soc., 1993, 115, 5115 Search PubMed.
  3. See, for example: D. Braga, F. Grepioni, P. J. Dyson, B. F. G. Johnson, P. Frediani, M. Bianchi and F. Piacenti, J. Chem. Soc., Dalton Trans., 1992, 2565 Search PubMed.
  4. See, for example: C. A. Cotton, D. J. Darensbourg, A. Fang, B. W. S. Kolthammer, D. Reed and J. L. Thompson, Inorg. Chem., 1981, 20, 4090 Search PubMed.
  5. See, for example: P. A. Bianconi, R. N. Vrtis, C. P. Rao, I. D. Williams, M. P. Engeler and S. J. Lippard, Organometallics, 1987, 6, 1968 Search PubMed; C. J. Cardin, D. J. Cardin, D. A. Morton-Blake, H. E. Parge and A. Roy, J. Chem. Soc., Dalton Trans., 1987, 1641 CrossRef CAS.
  6. G. K.-I. Magommedov, A. I. Gusev, A. S. Frenkel, V. G. Sirkin, L. I. Chaplina and S. N. Gourkova, Koord. Khim., 1976, 2, 257 Search PubMed; J. Votinsky, L. Benes, J. Klikorka, J. Kalousova, J. Horak and P. Lostak, J. Appl. Crystallogr., 1984, 17, 363 CrossRef CAS.
  7. M. Maekawa, M. Munakata, T. Kuroda-Sowa and K. Hachiya, Inorg. Chim. Acta, 1995, 232, 231 CrossRef CAS.
  8. D. Braga, F. Grepioni, C. M. Martin, E. Parisini, P. J. Dyson and B. F. G. Johnson, Organometallics, 1994, 13, 2170 CrossRef CAS.
  9. P. W. Dyer, P. J. Dyson, S. L. James and P. Suman, in preparation.
  10. P. J. Dyson, D. G. Humphrey, J. E. McGrady, D. M. P. Mingos and D. J. Wilson, J. Chem. Soc., Dalton Trans., 1995, 4039 RSC.
  11. P. J. Pye, K. Rossen, R. A. Reamer, N. N. Tsou, R. P. Volante and P. J. Reider, J. Am. Chem. Soc., 1997, 119, 6207 CrossRef CAS; K. Rossen, P. J. Pye, A. Maliakal and R. P. Volante, J. Org. Chem., 1997, 62, 6462 CrossRef CAS.
  12. H. J. Reich and D. J. Cram, J. Am. Chem. Soc., 1969, 91, 3505 CrossRef CAS.
  13. P. J. Dyson and P. Suman, unpublished work.
  14. E. C. Alyea, G. Ferguson and S. Kannan, Chem. Commun., 1998, 345 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.