Syntheses and structures of a new class of aza- and thio-ether macrocyclic d0 imido complexes

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Paul J. Wilson, Alexander J. Blake and Martin Schröder


Abstract

The synthesis and structures of a family of macrocyclic, d0 titanium imido complexes [Ti(NBut)(L)Cl2] (L = [9]aneN3, Me3[9]aneN3, [9]aneS3 or Me2[9]aneN2S) are reported; the new compounds are isolobal analogues of group 4 metallocene dichlorides.


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