Paul J. Wilson, Alexander J. Blake and Martin Schröder
The synthesis and structures of a family of macrocyclic, d0 titanium imido complexes [Ti(NBut)(L)Cl2] (L = [9]aneN3, Me3[9]aneN3, [9]aneS3 or Me2[9]aneN2S) are reported; the new compounds are isolobal analogues of group 4 metallocene dichlorides.