A two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu₃(4,7-phen)₃]³⁺ clusters: [{Cu₃(4,7-phen)₃}₂{Mo₁₄O₄₅}]

Abstract

The hydrothermal reaction of Cu(SO₄)·H₂O, MoO₃, 4,7-phenanthroline and water yields [{Cu₃(4,7-phen)₃}₂{Mo₁₄O₄₅}], a material exhibiting a two-dimensional network constructed from (Mo₆O₁₉)^2– and (Mo₈O₂₆)^4– clusters linked through planar cyclic {Cu₃(4,7-phen)₃³}⁺ clusters.

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