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DOI: 10.1039/A801495G (Paper) Reference Section for: Chem. Commun., 1998, 1363-1364

Synthesis and solid-state structure of [K3(thf)2{PH(Mes)}3]∞ (Mes = 2,4,6-Me3C6H2): the first potassium phosphanide with a polyhedral arrangement of K and P atoms

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Christoph Frenzel

Abstract

KPH(Mes) (Mes = 2,4,6-Me3C6H2), prepared from potassium and PH2(Mes) in refluxing toluene, crystallises from thf–pentane as [K3(thf)2{PH(Mes)}3]∞ 1, in which the basic structural feature is a chain of tetragonal pyramids of KP5 units, which share common edges, and two additional K atoms located over two adjacent edges of one trigonal face of the pyramid.

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