DOI: 10.1039/A801342J
(Paper)
Reference Section for: Chem. Commun., 1998, 1129-1130
A novel, internally-solvated phosphinomethanide; crystal structure of Li[C(SiMe3)2{P(C6H4CH2NMe2-2)2}]
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William Clegg, Simon Doherty, Keith Izod and Paul O’Shaughnessy
Abstract
Metallation of P{CH(SiMe3)2}(C6H4CH2NMe2-2)2 with BunLi yields a novel lithium phosphinomethanide in which the ligand exhibits an unprecedented tridentate PN2 coordination mode and in which there are no short contacts between lithium and the planar carbanion centre.
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