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DOI: 10.1039/A801269E (Paper) Reference Section for: Chem. Commun., 1998, 1013-1014

Dendritic rods with a poly(triacetylene) backbone: insulated molecular wires

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Albertus P. H. J. Schenning, Rainer E. Martin, Masato Ito, François Diederich, Albertus P. H. J. Schenning, Rainer E. Martin, Corinne Boudon, Jean-Paul Gisselbrecht and Maurice Gross

Abstract

Multinanometer long phenylacetylene-end-capped poly(triacetylene) (PTA) oligomers with dendritic side chains of generation one to three have been prepared; UV–VIS measurements indicate that there is no loss of π-electron conjugation along the PTA backbone in the higher generation compounds despite distortion from planarity due to the bulky dendritic wedges.

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