Solid state polymerization of the unsymmetrical [1]ferrocenophane Fe(η-C5H4)2SiMePh; synthesis of the first stereoregular organometallic polymer

(Note: The full text of this document is currently only available in the PDF Version )

John Rasburn, Daniel A. Foucher, William F. Reynolds and G. Julius Vancso


Abstract

Solid state polymerization of the [1]ferrocenophane Fe(η-C5H4)2SiMePh yields a stereoregular poly(ferrocenylmethylphenylsilane), the first example of a stereoregular organometallic polymer.


References

  1. H. H. Brintzinger, D. Fischer, R. Mülhaupt, B. Rieger and R. M. Waymouth, Angew. Chem., Int. Ed. Engl., 1995, 34, 1143 CrossRef CAS.
  2. J. P. Banovetz, K. M. Stein and R. M. Waymouth, Organometallics, 1991, 10, 3430 CrossRef CAS.
  3. I. Manners, Angew. Chem., Int. Ed. Engl., 1996, 35, 1602 CrossRef.
  4. I. Manners, Adv. Organomet. Chem., 1995, 37, 131 CAS.
  5. D. A. Foucher, B.-Z. Tang and I. Manners, J. Am. Chem. Soc., 1992, 114, 6246 CrossRef CAS.
  6. D. A. Foucher, R. Ziembinski, B.-Z. Tang, P. M. Macdonald, J. Massey, C. R. Jaeger, G. J. Vancso and I. Manners, Macromolecules, 1993, 26, 2878 CrossRef CAS.
  7. M. T. Nguyen, A. F. Diaz, V. V. Dement'ev and K. H. Pannell, Chem. Mater., 1993, 5, 1389 CrossRef CAS; M. Hmyne, A. Yasser, M. Escorne, A. Percheron-Guegan and F. Garnier, Adv. Mater., 1994, 6, 564 CrossRef CAS.
  8. S. Barlow, A. L. Rohl, S. Shi, C. M. Freeman and D. O'Hare, J. Am. Chem. Soc., 1996, 118, 7578 CrossRef CAS.
  9. A. G. Osborne, R. H. Whiteley and A. E. Meads, J. Organomet. Chem., 1980, 193, 345 CrossRef CAS.
  10. D. A. Foucher, R. Ziembinski, R. Petersen, J. K. Pudelski, M. Edwards, Y. Ni, J. Massey, C. R. Jaeger, G. J. Vancso and I. Manners, Macromolecules, 1994, 27, 3992 CrossRef CAS.
  11. R. Rulkens, A. J. Lough and I. Manners, J. Am. Chem. Soc., 1994, 116, 797 CrossRef CAS; Y. Ni, R. Rulkens and I. Manners, J. Am. Chem. Soc., 1996, 118, 4102 CrossRef CAS; P. Gómez-Elipe, P. M. Macdonald and I. Manners, Angew. Chem., Int. Ed. Engl., 1997, 36, 762 CrossRef CAS.
  12. M. Thakur, Solid-state Polymerisation in Encyclopaedia of Polymer Science and Engineering, ed. J. I. Kroshwitz, Wiley, New York, 1989, vol. 15 Search PubMed.
  13. J. Schultz, Polymer Materials Science, Prentice-Hall Inc., New Jersey, 1975, ch. 2, p. 113 Search PubMed.
  14. Y. Chatani, T. Uchida, H. Tadokoro, K. Hayashi, M. Nishi and S. Okamura, J. Macromol. Sci. B: Phys., 1968, 2, 567 Search PubMed.
  15. J. Rasburn, R. Petersen, T. Jahr, R. Rulkens, I. Manners and G. J. Vancso, Chem. Mater., 1995, 7, 871 CrossRef CAS.
  16. D. A. Foucher, A. J. Lough, I. Manners, J. Rasburn and G. J. Vancso, Acta. Crystallogr., Sect. C, 1995, 51, 580 CrossRef.
  17. F. A. Bovey, High Resolution NMR of Macromolecules, Academic Press, New York, 1972 Search PubMed.
  18. A. E. Tonelli, NMR and Polymer Microstructure: The Conformational Connection, VCH, New York, 1989 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.