Selective electrochemical magnesium and calcium sensors based on non-macrocyclic nitrogen-containing ferrocene ligands

(Note: The full text of this document is currently only available in the PDF Version )

Antony Chesney, Martin R. Bryce, Andrei S. Batsanov, Judith A. K. Howard and Leonid M. Goldenberg


Abstract

Ferrocene derivatives 1, 2a, 2b and 5 act as electrochemical sensors of Mg2+ and Ca2+ ions in acetonitrile solution in concentrations as low as 10 mol%: a new redox peak appears in the cyclic voltammogram, anodically shifted by 160–360 mV, with no interference from a large excess of several other metal salts; the single crystal X-ray structure of ligand 5 is reported.


References

  1. (a) G. W. Gokel, Chem. Soc. Rev., 1992, 21, 39 RSC; (b) P. D. Beer, Chem. Soc. Rev., 1989, 18, 409 RSC; (c) T. M. Swager and M. J. Marsella, Adv. Mater., 1994, 6, 595 CrossRef; (d) R. Dieing, V. Morisson, A. J. Moore, L. M. Goldenberg, M. R. Bryce, J.-M. Raoul, M. C. Petty, J. Garín, M. Savíron, I. K. Lednev, R. E. Hester and J. N. Moore, J. Chem. Soc., Perkin Trans. 2, 1587, 1996 Search PubMed.
  2. P. D. Beer, Adv. Inorg. Chem., 1992, 39, 79 Search PubMed; P. D. Beer and K. Y. Wild, Polyhedron, 1996, 15, 775 Search PubMed.
  3. M. P. Andrews, C. Blackburn, J. F. McAleer and V. D. Patel, J. Chem. Soc., Chem. Commun., 1987, 1122 Search PubMed; P. D. Beer, C. Blackburn, J. F. McAleer and V. D. Patel, Inorg. Chem., 1990, 29, 378 Search PubMed.
  4. P. D. Beer, H. Sikanyika, C. Blackburn and J. F. McAleer, J. Chem. Soc., Chem. Commun., 1989, 1831 Search PubMed.
  5. (a) P. D. Beer, H. Sikanyika, C. Blackburn and J. F. McAleer, J. Organomet. Chem., 1988, 350, C15 Search PubMed; (b) P. D. Beer, A. D. Keefe, H. Sikanyika, C. Blackburn and J. F. McAleer, J. Chem. Soc., Dalton Trans., 1990, 3289 Search PubMed.
  6. B. L. Tiwari and B. J. Howie, J. Met., 1988, 40, 102 Search PubMed.
  7. L. A. Blatter, A. Buri and J. A. S. McGuigan, J. Physiol., 1984, 418, 154 Search PubMed and references therein.
  8. Z. J. Zhang and W. R. Seitz, Anal. Chim. Acta, 1985, 171, 251 Search PubMed.
  9. K. Suzuki, K. Tohda, Y. Tanda, H. Ohzora, S. Nishihama, H. Inoue and T. Shirai, Anal. Chem., 1989, 61, 382 Search PubMed.
  10. (a) C. J. Richards, T. Damalidis, D. E. Hibbs and M. B. Hursthouse, Synlett., 1995, 74 Search PubMed; (b) T. Sammakia, H. A. Latham and D. R. Schaad, J. Org. Chem., 1995, 60, 10 Search PubMed; (c) C. J. Richards and A. W. Mulvaney, Tetrahedron: Asymmetry, 1996, 7, 1419 Search PubMed.
  11. A. I. Meyers and M. Shipman, J. Org. Chem., 1991, 56, 7098 Search PubMed.
  12. (a) S. R. Miller, D. A. Gustowski, Z. C. Chen, G. W. Gokel, L. Echegoyen and A. E. Kaifer, Anal. Chem., 1988, 60, 2021 Search PubMed; (b) A. E. Kaifer and S. Mendoza, in Comprehensive Supramolecular Chemistry, ed. G. Gokel, Pergamon, Oxford, 1996, vol. 1, p. 701 Search PubMed.
  13. E. J. Corey and K. Ishihara, Tetrahedron Lett., 1992, 33, 6807 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.